Arylsulfonylureas, processes for their preparation, and their use as herbicides and growth regulators

ABSTRACT

The invention relates to novel intermediates for the preparation of a certain group of novel phenylsulfonylurea herbicides, which herbicides are particularly advantageous for use in crop protection. The novel intermediate compounds are of the formula II ##STR1## and of the formula VI, ##STR2## as defined in the specification and claims. The intermediate compounds may be used to prepare herbicidal and plant growth regulating compounds of the formula I or salts thereof: ##STR3## as defined in the specification. The herbicides so obtained are particularly suitable for selectively controlling weeds.

DESCRIPTION

This application is a 371 of PCT/EP92/00304 filed Feb. 12, 1992. The invention relates to the field of crop protection agents, in particular selective herbicides and growth regulators of the type of the phenylsulfonylureas which are substituted by a heterocycle.

EP-A-007,687 has already disclosed, inter alia, sulfonylureas of the formula (1) ##STR4## in which R² is H, Cl, Br, F, (C₁ -C₃)alkyl, --NO₂, --SO₂ CH₃, --OCH₃, --SCH₂, --CF₃, --N(CH₃)₂, --NH₂ or --CN; R³ is H, Cl, Br, F or CH₃ ; X is CH or N, Q is O, S or optionally substituted NH; and Y and Z are H, Cl or various organic radicals. The compounds have been described as herbicides and plant growth regulators.

EP-A-0,291,851 and DE-A-3,900,472 have disclosed herbicidal and plant growth-regulating sulfonylureas of the formula (2) ##STR5## in which Z is F, Cl or Br, R¹ is H, optionally substituted alkyl, alkenyl, alkynyl or cycloalkyl, R² is H,CH₃ or C₂ H₅, R³ is H, F, Cl, Br, CH₃ or OCH₃, R⁴ is H, CH₃, (C₁ -C₄)alkoxy and X is CH or N.

U.S. Pat. No. 4,566,898 furthermore describes the sulfonylurea of the formula (3) ##STR6## as a herbicide which has outstanding properties, in particular for controlling black grass in barley and wheat.

Surprisingly, it has now been found that some iodinated arylsulfonylureas have advantageous properties.

The present invention therefore relates to compounds of the formula (I) and salts thereof, ##STR7## where Q is oxygen, sulfur or --N(R⁴)--, preferably O or S, in particular O;

W is oxygen or sulfur, preferably O;

Y and Z independently of one another are CH or N, where Y and Z are not simultaneously CH, preferably Y is CH or N and Z is N;

R is hydrogen; (C₁ -C₁₂)alkyl; (C₂ -C₁₀)alkenyl; (C₂ -C₁₀)alkynyl; (C₁ -C₆)alkyl, which is mono substituted to tetrasubstituted by radicals selected from the group comprising halogen, (C₁ -C₄)alkoxy, (C₁ -C₄)thioalkyl, --CN, (C₂ -C₅)alkoxycarbonyl and (C₂ -C₆)alkenyl; (C₃ -C₈)cycloalkyl which is unsubstituted or substituted by radicals selected from the group comprising (C₁ -C₄)alkyl, (C₁ -C₄)alkoxy, (C₁ -C₄)alkylthio and halogen; (C₅ -C₈)cycloalkenyl; phenyl (C₁ -C₄)alkyl which is unsubstituted or substituted in the phenyl radical; or a radical of the formulae A-1 to A-10 ##STR8## where X is O, S, S(O) or SO₂ ;

R² is hydrogen or (C₁ -C₃)alkyl;

R² is hydrogen, halogen, preferably chlorine, (C₁ -C₃)alkyl, (C₁ -C₃)alkoxy, where the two last-mentioned radicals are unsubstituted or monosubstituted or polysubstituted by halogen or (C₁ -C₃)alkoxy;

R³ is hydrogen, halogen, preferably chlorine, (C₁ -C₃)alkyl, (C₁ -C₃)alkoxy or (C₁ -C₃)alkylthio, where the abovementioned alkyl-containing radicals are unsubstituted or monosubstituted or polysubstituted by halogen or monosubstituted or disubstituted by (C₁ -C₃)alkoxy or (C₁ -C₃)alkylthio; or a radical of the formula NR⁵ R⁶, (C₁ -C₆)-cycloalkyl, (C₂ -C₄)alkenyl, (C₂ -C₄)alkynyl, (C₃ -C₄)alkenyloxy or (C₁ -C₆)alkynyloxy;

R⁴ is hydrogen, (C₁ -C₄)alkyl or (C₁ -C₄)alkoxy and

R⁵ and R⁶ independently of one another are hydrogen, (C₁ -C₄)alkyl, (C₃ -C₄)alkenyl, (C₁ -C₄)haloalkyl or (C₁ -C₄)alkoxy.

In formula (I) and in what follows, alkyl, alkoxy, haloalkyl, alkylamino and alkylthio radicals as well as the corresponding unsaturated and/or substituted radicals can in each case be straight-chain or branched. Alkyl radicals, also in composite meanings such as alkoxy, haloalkyl etc., are, for example, methyl, ethyl, n- or i-propyl, n-, i-, t- or 2-butyl etc. Alkenyl and alkynyl radicals have the meanings of the unsaturated radicals which are possible and which correspond to the alkyl radicals, such as, for example, 2-propenyl, 2- or 3-butenyl, 2-propynyl and 2- or 3-butynyl. Halogen is fluorine, chlorine, bromine or iodine. Aryl is preferably a carbocyclic or heterocyclic aromatic ring which can optionally be fused with an aliphatic or aromatic ring; in particular, aryl is phenyl. Substituted phenyl is phenyl which is substituted for example by one or more, preferably one to three, radicals selected from the group comprising halogen, (C₁ -C₄)alkyl, (C₁ -C₄)alkoxy, (C₁ -C₄)haloalkyl, (C₁ -C₄)thioalkyl, (C₂ -C₅)alkoxycarbonyl, (C₂ -C₅)alkylcarbonyloxy, carboxamide, (C₂ -C₅)alkylcarbonylamino, (C₂ -C₅)alkylaminocarbonyl, di-[(C₁ -C₄)alkyl]aminocarbonyl and nitro. The same applies analogously to substituted aryl.

The compounds of the formula (I) can form salts in which the hydrogen of the --SO₂ --NH-- group is replaced by a cation which is suitable for agriculture. Examples of these salts are metal salts, in particular alkali metal salts or alkaline earth metal salts, but also ammonium salts or salts with organic amines. Salt formation can also be effected by an addition reaction of a strong acid with the heterocycle moiety of the compounds of the formula (I). Examples of acids which are suitable for this purpose are HCl, HNO₃, trichloroacetic acid, acetic acid or palmitic acid.

Some compounds of the formula (I) can contain one or more asymmetric carbon atoms or else double bonds which are not mentioned individually in the formula (I). However, formula (I) embraces all possible stereoisomers which are defined by their specific spatial form such as enantiomers, diastereomers, Z and E isomers, which can be obtained from mixtures of the stereoisomers by customary methods or, alternatively, by stereoselective reactions in combination with the use of stereochemically pure starting materials. The invention thus relates to the stereo-isomers mentioned in pure form and also their mixtures.

Compounds of the formula (I) according to the invention, or salts thereof, which are of particular interest are those where

R is hydrogen; (C₁ -C₆)alkyl; (C₂ -C₆)alkenyl; (C₂ -C₆)-alkynyl; (C₁ -C₄)alkyl which is monosubstituted to tetra-substituted, preferably monosubstituted, by radicals selected from the group comprising halogen, (C₁ -C₂)alkoxy, (C₁ -C₂)thioalkyl, (C₂ -C₃)alkoxycarbonyl and (C₂ -C₄)alkenyl; (C₅ -C₆)cycloalkyl which is unsubstituted or substituted by radicals selected from the group comprising (C₁ -C₄)alkyl, (C₁ -C₄)alkoxy, (C₁ -C₄)alkylthio and halogen; (C₅ -C₆)cycloalkenyl; benzyl which is unsubstituted or substituted in the phenyl radical by one to three radicals selected from the group comprising halogen, (C₁ -C₂)alkyl, (C₁ -C₂)alkoxy, (C₁ -C₂)haloalkyl, (C₁ -C₂)thioalkyl and (C₂ -C₄)alkoxycarbonyl, or a radical of the abovementioned formulae A-1 to A-10, where

X is O, S, S(O) or SO₂, preferably O.

Compounds of the formula (I) according to the invention, or salts thereof, which are of particular interest are those where

R¹ is hydrogen or CH₃ ;

R² is hydrogen, halogen, preferably chlorine, (C₁ -C₂)alkyl, (C₁ -C₂)alkoxy, where the two last-mentioned radicals are unsubstituted or monosubstituted or polysubstituted by halogen or (C₁ -C₃)alkoxy;

R³ is hydrogen, halogen, preferably chlorine, (C₁ -C₂)alkyl, (C₁ -C₂)alkoxy or (C₁ -C₂)alkylthio, where the abovementioned alkyl-containing radicals are unsubstituted or monosubstituted or polysubstituted by halogen or monosubstituted or disubstituted by (C₁ -C₂)alkoxy or (C₁ -C₂)alkylthio; or a radical of the formula NR⁵ R⁶ ;

R⁴ is hydrogen or (C₁ -C₂)alkyl and

R⁵ and R⁶ independently of one another are hydrogen or (C₁ -C₂)alkyl.

Preferred compounds of the formula (I) according to the invention or salts thereof are those in which

W is oxygen and

R¹ is hydrogen or CH₃.

Particularly preferred compounds of the formula (I) or salts thereof are those in which

Y is CH or N,

Z is N and

R² is hydrogen, CH₃, CH₂ CH₃, OCH₃, OCH₂ CH₃, OCHF₂, Cl and

R³ is hydrogen, CH₃, CH₂ CH₃, OCH₃, OCH₂ CH₃, OCHF₂, NH(CH₃), N(CH₃)₂, CF₃, OCH₂ CF₃ or Cl.

Other preferred compounds according to the invention are those which exhibit a combination of the abovementioned preferred features.

The present invention furthermore relates to processes for the preparation of the compounds of the formula (I) or salts thereof, which comprise

a) reacting a compound of the formula (II) ##STR9## with a heterocyclic carbamate of the formula (III) ##STR10## where R' is unsubstituted or substituted aryl or alkyl, preferably unsubstituted or substituted phenyl or (C₁ -C₄)alkyl, in particular phenyl or methyl, or

b) reacting a phenylsulfonyl carbamate of the formula (IV) ##STR11## with an aminoheterocycle of the formula (V) ##STR12## c) reacting a sulfonyl isocyanate of the formula (VI) ##STR13## with an aminoheterocycle of the formula (V) mentioned under b).

The compounds of the formula (II) and (III) are reacted by means of base catalysis in an inert solvent, such as, for example, acetonitrile, dioxane or tetrahydrofuran at temperatures of between 0° C. and the boiling point of the solvent. 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) is preferably used as the base.

The sulfonamides (II) are novel compounds; this invention also relates to these compounds and to their preparation (see Tables 1a and 1b further below). They are obtained starting from corresponding sulfonyl halides, preferably corresponding sulfochlorides, which react either directly with ammonia or with tert.-butylamine, followed by elimination of the protective groups, for example by treatment with trifluoroacetic acid, to give the sulfonamides of the formula (II). The sulfonyl halides which can be used in the process can be obtained from the corresponding anilines by diazotization and exchange of the diazo group with sulfur dioxide in the presence of a catalyst such as copper(I) chloride in hydrochloric acid or acetic acid, cf. Meerwein, Chem. Ber. 90, 841-52 (1957).

The carbamates of the formula (III) can be prepared by methods as are described in the South African Patent Applications 82/5671 and 82/5045 (or EP-A-0,072,347 and EP-A-0,070,802, respectively).

The compounds (IV) are preferably reacted with the amino-heterocycles (V) in inert, aprotic solvents, such as, for example, dioxane, acetonitrile or tetrahydrofuran, at temperatures of between 0° C. and the boiling point of the solvent. The starting compounds required, of the formula (V), are known or can be prepared by methods known in principle, see "The Chemistry of Heterocyclic Compounds", Vol. XVI, (1962), Interscience Publ., New York & London, and Supplement I of this manual. Amino-substituted triazine derivatives are reviewed by Smolin and Rapaport in "The Chemistry of Heterocyclic Compounds", Vol. XIII, (1959), Interscience Publ., New York & London. The iodinated phenylsulfonyl carbamates (IV) are obtained analogously to processes given in EP-A-0,044,808 or EP-A-0,237,292.

The iodinated arylsulfonyl isocyanates of the formula (VI) are novel compounds and also a subject of the invention. They can be prepared analogously to methods of EP-A-0,184,385 and reacted with the abovementioned amino-heterocycles of the formula (V).

The salts of the compounds of the formula (I) are preferably prepared in inert solvents, such as, for example, water, methanol, dichloromethane or acetone, at temperatures of 0°-100°. Examples of suitable bases for the preparation of the salts according to the invention are alkali metal carbonates, such as potassium carbonate, alkali metal hydroxides and alkaline earth metal hydroxides, ammonia or ethanolamine. Acids which are particularly suitable for salt formation are HCl, HNO₃, trichloroacetic acid, acetic acid or palmitic acid.

The compounds of the formula (I) according to the invention have an excellent herbicidal activity against a broad range of economically important monocotyledon and dicotyledon weeds. The active substances act equally well on perennial weeds which produce shoots from rhizomes, rootstocks or other perennial organs and which cannot be easily controlled. In this context, it does not matter if the substances are applied before sowing, as a pre-emergence treatment or post-emergence treatment. Some representatives of the monocotyledon and dicotyledon weed flora which can be controlled by the compounds according to the invention may be mentioned individually as examples, but this is not to be taken to mean a restriction to certain species.

The monocotyledon weed species controlled include, for example, Avena, Lolium, Alopecurus, Phalaris, Echinochloa, Digitaria, Setaria etc. and Cyperus species from the annual group, and the perennial species include Agropyron, Cynodon, Imperata and Sorghum etc., and also perennial Cyperus species.

Of the dicotyledon weed species, the range of action covers, for example, Galium, Viola, Veronica, Lamium, Stellaria, Amaranthus, Sinapis, Ipomoea, Matricaria, Abutilon, Sida etc. from the annual plants and Convolvulus, Cirsium, Rumex, Artemisia etc. from the perennial weeds.

Excellent control of weeds occurring under the specific culture conditions in rice, such as, for example, Sagittaria, Alisma, Eleocharis, Scirpus, Cyperus etc., by the active substances according to the invention is also possible.

If the compounds according to the invention are applied to the soil surface before germination, either emergence of the weed seedlings is prevented completely, or the weeds grow until they have reached the cotyledon stage but growth then comes to a standstill and, after a period of three to four weeks, the plants eventually die completely. When, in the post-emergence method, the active substances are applied to the green parts of the plants, growth also stops dramatically very soon after the treatment, and the weed plants remain in the growth stage of the time of application, or, after a certain period of time, die more or less rapidly so that competition by the weeds, which is detrimental for the crop plants, can thus be prevented at a very early stage and in a sustained manner by using the novel compounds according to the invention.

Even though the compounds according to the invention have an excellent herbicidal activity against monocotyledon and dicotyledon weeds, crop plants of economically important crops such as, for example, wheat, barley, rye, maize, rice, sugar beet, cotton and soya, are damaged to a negligible extent only, or not at all. Thus, the present compounds are very suitable for selectively controlling undesired plant growth in agricultural plantations of useful plants.

In addition, the compounds according to the invention have plant growth-regulating properties in crop plants. They intervene in the plant metabolism in a regulating manner and can thus be employed for facilitating harvesting, such as, for example, by provoking desiccation, abscission and stunted growth. Furthermore, they are suitable for generally regulating and inhibiting undesired vegetative growth, without simultaneously destroying the plants. Inhibition of vegetative growth plays an important role in many monocotyledon and dicotyledon crops because lodging can be reduced hereby, or prevented completely.

The compounds according to the invention can be formulated in many ways, depending on the prevailing biological and/or chemicophysical parameters. Examples of possible formulations are the following: wettable powders (WP), water-soluble powders (SP), water-soluble concentrates, emulsifiable concentrates (EC), emulsions (EW) such as oil-in-water and water-in-oil emulsions, sprayable solutions or emulsions, suspension concentrates (SC), dispersions on an oil or water basis, oil-miscible solutions, suspoemulsions, capsule suspensions (CS), dusts (DP), seed-dressing agents, granules for broadcasting and soil application, granules (GR) in the form of microgranules, spray granules, coated granules and adsorption granules, water-dispersible granules (WG), water-soluble granules (SG), ULV formulations, microcapsules and waxes.

These individual types of formulation are known in principle and are described, for example, in: Winnacker-Kuchler, "Chemische Technologie", [Chemical Technology], Volume 7, G. Hauser Verlag Munich, 4th Ed. 1986; van Valkenburg, "Pesticides Formulations", Marcel Dekker N.Y., 2nd Ed. 1972-73; K. Martens, "Spray Drying Handbook", 3rd Ed. 1979, G. Goodwin Ltd. London.

The formulation auxiliaries required, such as inert materials, surfactants, solvents and further additives, are also known and are described, for example, in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Darland Books, Galdwell N.J.; H. v. Olphen, "Introduction to Clay Colloid Chemistry"; 2nd Ed., J. Wiley & Sons, N.Y.; Marsden, "Solvents Guide", 2nd Ed., Interscience, N.Y. 1950; McCutcheon's "Detergents and Emulsifiers Annual" MG Publ. Corp., Ridgewood N.J.; Sisley and Wood, "Encyclopedia of Surface Active Agents", Chem. Publ. Co. Inc., N.Y. 1964; Schonfeldt, "Grenzflachenaktive Athylenoxidaddukte", [Surface-active Ethylene Oxide Adducts], Wiss. Verlagsgesell., Stuttgart 1976; Winnacker-Kuchler, "Chemische Technologie", [Chemical Technology], Volume 7, G. Hauser Verlag Munich, 4th Ed. 1986.

Wettable powders are preparations which are uniformly dispersible in water and which, besides the active substance, also contain wetting agents, for example, polyoxyethylated alkylphenols, polyoxyethylated fatty alcohols and fatty a mines, fatty alcohol polyglycol ether sulfates, alkanesulfonates or alkylarylsulfonates, and dispersing agents, for example sodium ligninsulfonate, sodium 2,2'-dinaphthylmethane-6,6,-disulfonate, sodium dibutylnaphthalenesulfonate and also sodium oleylmethyltauride, in addition to a diluent or inert substance.

Emulsifiable concentrates are prepared, for example, by dissolving the active substance in an organic solvent, for example butanol, cyclohexanone, dimethylformamide, xylene and also higher-boiling aromatics or hydrocarbons, with the addition of one or more emulsifiers. Emulsifiers which can be used are, for example: calcium salts of alkylarylsulfonic acids, such as calcium dodecylbenzenesulfonate or non-ionic emulsifiers, such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide/ethylene oxide condensation products (for example block polymers), alkyl polyglycol ethers, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters or polyoxyethylene sorbitol esters.

Dusts are obtained by grinding the active substance with finely divided solid substances, for example talc or natural clays, such as kaolin, bentonite or pyrophyllite, or diatomaceous earth.

Granules can be produced either by spraying the active substance onto adsorptive, granulated inert material or by applying active substance concentrates onto the surface of carriers such as sand, kaolinites or of granulated inert material, by means of binders, for example polyvinyl alcohol, sodium polyacrylate or alternatively mineral oils. Suitable active substances can also be granulated in the manner which is conventional for the production of fertilizer granules, if desired in a mixture with fertilizers.

Disk granules, fluidized-bed granules, extruder granules and spray granules can be prepared by conventional methods; see, for example, methods in "Spray Drying Handbook", 3rd Ed. 1979, G. Goodwin Ltd., London; J. E. Browning, "Agglomeration", Chemical and Engineering 1967, pages 147 et seq.; "Perry's Chemical Engineer's Handbook", 5th Ed., McGraw-Hill, New York 1973, p. 8-57.

Further information on the formulation of crop protection agents can be found, for example, in G. G. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York, 1961, pages 81-96 and J. D. Freyer's, A. Evans, "Weed Control Bandbook", 5th Ed., Blackwell Scientific Publications, Oxford, 1968, pages 101-103.

The active substance concentration in wettable powders is, for example, about 10 to 90% by weight; the remainder to 100% by weight is composed of conventional formulation components. In the case of emulsifiable concentrates, the active substance concentration can be about 1 to 80% by weight. Formulations in the form of dusts usually contain 1 to 20% by weight of active substance, sprayable solutions about 0.2 to 20% by weight. In the case of granules the active substance content depends partly on whether the active compound is liquid or solid. The water-dispersible granules usually contain between 10 and 90% by weight of active substance.

In addition, the active substance formulations mentioned contain, if appropriate, the adhesives, wetting agents, dispersing agents, emulsifiers, penetrants, solvents, fillers or carriers which are conventional in each case.

Based on these formulations, it is also possible to prepare combinations with other substances which are active in arable farming, for example pesticides such as insecticides, acaracides, fungicides and herbicides, and/or fertilizers and/or growth regulators, for example in the form of a readymix or as a tank mix.

In particular, the compounds of the formula (I) according to the invention can be used together with further herbicides as are known, for example, from Weed Research 26, 441-5 (1986) or "The Pesticide Manual", 9th Edition, The British Crop Protection Council, 1990, England. The following active substances may be mentioned as examples of herbicides which are known from the literature and which can be combined according to the invention with the compounds of the formula (I) (the common name, or manufacturer's code, of each of the active substances is in bold print and the chemical name is then in ordinary typeface, see scheme):

Common name (or Manufacturer's code) Chemical name [Scheme]

AC 263222 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-methyl-3-pyridinecarboxylic acid; acetochlor 2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl)acetamide;

acifluorfen 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoic acid;

aclonifen 2-chloro-6-nitro-3-phenoxyaniline;

AKB 7088 methyl [[[1- [5- [2- chloro-4-(trifluoromethyl)phenoxy]-2-nitrophenyl]-2-methoxyethylidene]amino]oxy]acetate;

alachlor 2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide;

alloxydim methyl 3-[1-(allyloxyimino)-butyl]-4-hydroxy-6,6-dimethyl-2-cyclohex-3-enecarboxylate;

ametryn N-ethyl-N'-(1-methylethyl)-6-(methylthio)-1,3,5-triazine-2,4-diamine;

amidosulfuron 1-[N-Methyl-N-(methylsulfonyl)-aminosulfonyl]-3-(4,6-dimethoxypyrimidin-2-yl)urea;

amitrole 1H-1,2,4-triazol-3-amine;

AMS ammonium sulfamate;

anilofos S-[2-[(4-chlorophenyl)(1-methylethyl)amino]-2-oxoethyl] O,O-dimethylphosphorodithioate;

asulam methyl [(4-aminophenyl)sulfonyl]carbamate;

atrazine 6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4-diamine;

aziprotryn 2-azido-N-(1-methylethyl)-6-methylthio-1,3,5-triazin-2-amine;

barban 4-chloro-2-butynyl 3-chlorophenylcarbamate;

BAS 516 H 5-fluoro-2-phenyl-4H-3,1-benzoxazin-4-one;

benazolin 4-chloro-2-oxo-3(2H)-benzothiazoleacetic acid;

benfluralin N-butyl-N-ethyl-2,6-dinitro-4-(trifluoromethyl)benzenamine;

benfuresate 2,3-dihydro-3,3-dimethylbenzofuran-5-yl ethanesulfonate;

bensulfuron-methyl methyl 2-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]methyl]benzoate;

bensulideO,O-bis-(1-methylethyl)S-[2-[(phenylsulfonyl)amino]ethyl]phosphorodithioate;

bentazone 3-(1-methylethyl)-1H-2,1,3-benzothiadiazin-4(3H)-one, 2,2-dioxide;

benzofenap 2-[[4-(2,4-dichloro-3-methylbenzoyl)-1,3-dimethyl-1H-pyrazol-5-yl]oxy]-1-(4-methylphenyl)ethanone;

benzofluor N-[4-(ethylthio)-2-(trifluoromethyl)phenyl]-methanesulfonamide;

benzoylprop-ethylethylN-benzoyl-N-(3,4-dichlorophenyl)alaninate;

benzthiazuron N-2-benzothiazolyl-N'-methylurea;

bialaphos 4-(hydroxymethylphosphinyl)-L-2-aminobutanoyl-L-alanyl-L-alanine;

bifenox methyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate;

bromacil bromo-6-methyl-3-(1-methylpropyl)-2,4(1H,3H)pyrimidinedione;

bromobutide N-[(1,1-dimethyl)methylphenyl]-2-bromo-3,3-dimethylbutyramide;

bromofenoxim 3,5-dibromo-4-hydroxybenzaldehyde O-(2,4-dinitrophenyl)oxime;

bromoxynil 3,5-dibromo-4-hydroxybenzonitrile;

bromuron N'-(4-bromophenyl)-N,N-dimethylurea;

buminafos dibutyl [1-(butylamino)cyclohexyl]phosphonate;

butachlor N-(butoxymethyl)-2-chloro-N-(2,6-diethylphenyl)acetamide;

butamifos O-ethyl O-(5-methyl-2-nitrophenyl) (1-methylpropyl)phosphoramidothioate;

butenachlor (Z)-N-but-2-enyloxymethyl-2-chloro-2',6'-diethylacetanilide;

busoxinone 3-[5-(1,1-dimethylethyl)-isoxazol-3-yl]-4-hyroxy-1-methyl-2-imidazolidinone; buthidazole 3-[5-(1,1-dimethylethyl)-1,3,4-thiadiazol-2-yl]-4-hydroxy-1-methyl-2-imidazolidinone;

butralin 4-(1,1-dimethylethyl)-N-(1-methylpropyl)-2,6-dinitrobenzenamine;

butylate S-ethyl bis(2-methylpropyl)carbamothioate;

C 4874 (tetrahydro-2-furanyl)methyl 2-[4-[(6-chloro-2-quinoxalinyl)oxy]phenoxy]propanoate;

carbetamide (R)-N-ethyl-2-[[(phenylamino)carbonyl]-oxy]propanamide;

CDAA 2-chloro-N,N-di-2-propenylacetamide;

CDEC 2-chloroallyl diethyldithiocarbamate;

CGA 184927 2-propynyl 2-[4-[(5-chloro-3-fluoro-2-pyridinyl)oxy]phenoxy]propanoate;

chlomethoxyfen 4-(2,4-dichlorophenoxy)-2-methoxy-1-nitrobenzene;

chloramben 3-amino-2,5-dichlorobenzoic acid;

chlorbromuron 3-(4-bromo-3-chlorophenyl)-1-methoxy-1-methylurea;

chlorbufaml-methyl-2-propynyl (3-chlorophenyl)carbamate;

chlorfenac 2,3,6-trichlorobenzeneacetic acid;

chlorflurecol-methyl methyl 2-chloro-9-hydroxy-9H-fluorene-9-carboxylate;

chloridazon 5-amino-4-chloro-2-phenyl-3(2H)-pyridazinone;

chlorimuron ethyl ethyl 2-[[[[(4-chloro-6-methoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]benzoate;

chlornitrofen 1,3,5-trichloro-2-(4-nitrophenoxy)benzene;

chlorotoluron N'-(3-chloro-4-methylphenyl)-N,N-dimethylurea;

chloroxuron N'-[4-(4-chlorophenoxy)phenyl]-N,N-dimethylurea;

chlorpropham 1-methylethyl 3-chlorophenylcarbamate;

chlorsulfuron 2-chloro-N-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]benzenesulfonamide;

chlorthal-dimethyl dimethyl 2,3,5,6-tetrachloro-1,4-benzenedicarboxylate;

chlorthiamid 2,6-dichlorobenzenecarbothioamide;

cinmethylin exo-1-methyl-4-(1-methylethyl)-2-[(2-methylphenyl)methoxy]-7-oxabicyclo[2.2.1]heptane;.

cinosulfuron 1-(4,6-dimethoxy-1,3,5-triazin-2-yl)3-[2 -(2-methoxyethoxy)phenylsulfonyl]urea;

clethodim (E,E)-2-[1-[[(3-chloro-2-propenyl)oxy]imino]-propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one;

clomazone 2-[(2-chlorophenyl)methyl]-4,4-dimethyl-3-isoxazolidinone;

clomeprop [(2,4-dichloro-3-methylphenyl)oxy]-2-propionanilide;

cloproxydim (E,E)-2-[1-[[(3-chloro-2-propenyl)oxy]-imino]butyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one;

clopyralid 3,6-dichloro-2-pyridinecarboxylic acid;

cyanazine 2-[[4-chloro-6-(ethylamino)-1,3,5-triazin-2-yl]amino]-2-methylpropanenitrile;

cycloate S-ethyl cyclohexylethylcarbamothioate;

cycloxydim 2-[1-(ethoxyimino)butyl]-5-(tetrahydrothiopyran-3-yl)-3-hydroxy-2-cyclohexen-1-one;

cycluron 3-cyclooctyl-1-dimethylurea;

cyperquat 1-methyl-4-phenylpyridinium;

cyprazine 2-chloro-4-(cyclopropylamino)-6-(isopropylamino)-s-triazine;

cyprazole N-[5-(2-chloro-1,1-dimethylethyl)-1,3,4-thiadiazol-2-yl]-cyclopropanecarboxamide;

2,4-DB 4-(2,4-dichlorophenoxy)butanoic acid;

dalapon 2,2-dichloropropanoic acid;

desmediphamethyl[3-[[(phenylamino)carbonyl]oxy]phenyl]-carbamate;

desmetryn 2-(isopropylamino)-4-(methylamino)-6-(methylthio)s-triazine;

di-allate S-(2,3-dichloro-2-propenyl)bis(1-methylethyl)carbamothioate;

dicamba 3,6-dichloro-2-methoxybenzoic acid;

dichlobenil 2,6-dichlorobenzonitrile;

dichlorprop 2-(2,4-dichlorophenoxy)propanoic acid;

diclofop-methyl methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]-propanoate;

diethatyl N-(chloroacetyl)-N-(2,6-diethylphenyl)glycine;

difenoxuron N'-[4-(4-methoxyphenoxy)phenyl]-N,N-dimethylurea;

difenzoquat 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium;

diflufenican N-(2,4-difluorophenyl)-2-[3-(trifluoromethyl)-phenoxy]-3-pyridinecarboxamide;

dimefuron N'-[3-chloro-4-[5-(1,1-dimethylethyl)-2-oxo-1,3,4-oxadiazol-3(2H)-yl]phenyl]-N,N-dimethylurea;

dimethachlor 2-chloro-N-(2,6-dimethylphenyl)-N-(2-methoxyethyl)acetamide;

dimethametryn N-(1,2-dimethylpropyl)-N'-ethyl-6-(methylthio)-1,3,5-triazine-2,4-diamine;

dimethipin2,3-dihydro-5,6-dimethyl-1,4-dithiin,1,1,4,4-tetraoxide;

dinitramine N³ ,N³ -diethyl-2,4-dinitro-6-(trifluoromethyl)-1,3-benzenediamine;

dinoseb 2-(1-methylpropyl)-4,6-dinitrophenol;

dinoterb 2-(1,1-dimethylethyl)-4,6-dinitrophenol;

diphenamid N,N-dimethyl-2,2-diphenylacetamide;

dipropetryn 6-ethylthio-N,N'-bis(1-methylethyl)-1,3,5-triazine-2,4-diamine;

diquat 6,7 dihydrodipyrido[1,2-a:2',1'-c]pyrazinediium,

dithiopyr 2-(difluoromethyl)-4-(2-methylpropyl)-6-(trifluoromethyl)-3,5-pyridinedicarbothioic acid;

diuron N'-(3,4-dichlorophenyl)-N,N-dimethylurea;

DNOC 2-methyl-4,6-dinitrophenol;

DPX-A7881methyl 2-[[[[(4-ethoxy-6-N-(methyl)amino-1,3,5-triazin-2-yl]amino]carbonyl]amino]sulfonyl]benzoate;

DPX-E9636 N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]-carbonyl]-3-(ethylsulfonyl)-2-pyridinesulfonamide;

dymron N-(4-methylphenyl)-N'-(1-methyl-1-phenylethyl)urea;

eglinazine-ethyl ethyl N-[4-chloro-6-(ethylamino)-1,3,5-tria-zin-2-yl]glycinate;

EL 177 5-cyano-1-(1,1-dimethylethyl)-N-methyl-3H-pyrazole-4-carbo xamide;

endothal 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid;

EPTC S-ethyl dipropylcarbamothioate;

esprecarb S-(methylphenyl) N-ethyl-N-(1,2-dimethyl)propylcarbamothioate;

ethalfluralin N-ethyl-N-(2-methyl-2-propenyl)-2,6 -dinitro-4-(trifluoromethyl)benzenamine;

ethidimuron N-[5-(ethylsulfonyl)-1,3,4-thiadiazol-2-yl]-N,N'-dimethylurea;

ethiozin 4-amino-6-(1,1-dimethylethyl)-3-(ethylthio)-1,2,4-triazin-5(4H)-one;

ethofumesate 2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl methanesulfonate;

F 5231 N-[2-chloro-4-fluoro-5-[4-(3-fluoropropyl)-4,5-dihydro-5-oxo-1H-tetrazol-1-yl]phenyl]ethanesulfonamide;

fenoprop 2-(2,4,5-trichlorophenoxy)propanoic acid;

fenoxaprop-ethyl ethyl 2-[4-[(6-chloro-2-benzoxazolyl)oxy]-phenoxy]propanoate;

fenuron N,N-dimethyl-N'-phenylurea;

flamprop-methyl methyl N-benzoyl-N-(3-chloro-4-fluorophenyl)-alaninate;

flazasulfuron 1-(4,6-dimethoxypyrimidin-2-yl)-3-[3-(trifluoromethyl)-2-pyridylsulfonyl]urea;

fluazifop-butyl butyl 2-[4-[[5-(trifluoromethyl)-2-pyridinyl]-oxy]phenoxy]propanoate;

fluchloralin N-(2-chloroethyl)-2,6-dinitro-N-propyl-4-(trifluoromethyl)benzenamine;

flumeturon N,N-dimethyl-N'-[3-(trifluoromethyl)phenyl]-urea;

flumipropyn 2-[4-chloro-2-fluoro-5-[(1-methyl-2-propynyl)oxy]phenyl-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)dione;

fluorodifen 2-nitro-1-(4-nitrophenoxy)-4-(trifluoromethyl)benzene;

fluoroglycofen-ethyl ethyl carboxymethyl 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate;

fluridone 1-methyl-3-phenyl-5-[3-(trifluoromethyl)phenyl]-4(1H)-pyridinone;

flurochloridone 3-chloro-4-(chloromethyl)-1-[3-(trifluoromethyl)phenyl]-2-pyrrolidinone;

fluroxypyr 4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyacetic acid;

flurtamone 5-(methylamino)-2-phenyl-4-[3-(trifluoromethyl)phenyl]-3(2H)-furanone;

fomesafen 5-[2-chloro-4-(trifluoromethyl)phenoxy]-N-(methylsulfonyl)- 2-nitrobenzamide;

fosamine ethyl hydrogen carbamoylphosphonate;

furyloxyfen 3-[5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrophenoxy]-tetrahydrofuran;

glufosinate 4-[hydroxy(methyl)phosphinoyl]homoalanine;

glyphosate N-(phosphonomethyl)glycine;

halosaten 5-[6-chloro-2-fluoro-4-(trifluoromethyl)phenoxy]-N-(ethylsulfonyl)-2-nitrobenzamide;

haloxyfop 2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]propanoic acid;

hexazinone 3-cyclohexyl-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione;

Hw 52 N-(2,3-dichlorophenyl)-4-(ethoxymethoxy)benzamide;

imazamethabenz-methyl methyl 6-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)-m-toluate and methyl 6-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)-p-toluate;

imazapyr 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-3-pyridinecarboxylic acid;

imazaquin 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-3-quinolinecarboxylic acid;

imazethapyr 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-ethyl-3-pyridinecarboxylic acid;

imazosulfuron 2-chloro-N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]imidazo[1,2-a]pyridine-3-sulfonamide;

ioxynil 4-hydroxy-3,5-diiodobenzonitrile;

isocarbamid N-(2-methylpropyl)-2-oxo-1-imidazolidinecarboxamide;

isopropalin 4-(1-methylethyl)-2,6-dinitro-N,N-dipropylbenzenamine;

isoproturon N-[4-(methylethyl)phenyl]-N',N'-dimethylurea;

isouron N'-[5-(1,1-dimethylethyl)-3-isoxazolyl]-N,N-dimethylurea;

isoxaben N-[3-(1-ethyl-1-methylpropyl)-5-isoxazolyl]-2,6-dimethoxybenzamide;

isoxapyrifop 2-[2-[4-[(3,5-dichloro-2-pyridinyl)oxy]-phenoxy]-1-oxopropyl]-isoxazolidine;

karbutilate 3-[[(dimethylamino)carbonyl]amino]phenyl (1,1-dimethylethyl)carbamate;

lactofen 2-ethoxy-1-methyl-2-oxoethyl 5-[2-chloro-4 -(trifluoromethyl)phenoxy]-2-nitrobenzoate;

lenacil 3-cyclohexyl-6,7-dihydro-1H-cyclopentapyrimidine-2,4(3H,5H)-dione;

linuron N'-(3,4-dichlorophenyl)-N-methoxy-N-methylurea;

MCPA (4-chloro-2-methylphenoxy)acetic acid;

MCPB 4-(4-chloro-2-methylphenoxy)butanoic acid;

mecoprop 2-(4-chloro-4-methylphenoxy)propanoic acid;

mefenacet 2-benzothiazol-2-yloxy-N-methylacetanilide;

mefluidide N-[2,4-dimethyl-5-[[trifluoromethyl)sulfonyl]amino]phenyl]acetamide;

metamitron 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5(4H)one;

metazachlor 2-chloro-N-(2,6-dimethylphenyl)-N-(1(H)-pyrazol-1-ylmethyl)acetamide;

methabenzthiazuron 1,3-dimethyl-3-(2-benzothiazolyl)urea;

metham methylcarbamodithioic acid;

methazole 2-(3,4-dichlorophenyl)-4-methyl-1,2,4-oxadiazolidine-3,5-dione;

methoxyphenone (4-methoxy-3-methylphenyl)(3-methylphenyl)methanone;

methyldymron N-methyl-N'-(1-methyl-1-phenylethyl)-N-phenylurea;

metobromuron N'-(4-bromophenyl)-N-methoxy-N-methylurea;

metolachlor 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide;

metoxuron N'-(3-chloro-4-methoxyphenyl)-N,N-dimethylurea;

metribuzin 4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one;

metsulfuron-methyl methyl 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]-benzoate;

MH 1,2-dihydro-3,6-pyridazinedione;

molinate S-ethyl hexahydro-1H-azepine-1-carbothioate;

monalide N-(4-chlorophenyl)-2,2-dimethylpentanamide;

monolinuron 3-(4-chlorophenyl)-1-methoxy-1-methylurea;

monuron N'-(4-chlorophenyl)-N,N-dimethylurea;

MT 128 6-chloro-N-(3-chloro-2-propenyl)-5-methyl-N-phenyl-3-pyridazinamine;

MT 5950 N-[3-chloro-4-(1-methylethyl)phenyl]-2-methylpentanamide;

naproanilide 2-(2-naphthalenyloxy)-N-phenylpropanamide;

napropamide N,N-diethyl-2-(1-naphthalenyloxy)propanamide;

naptalam 2-[(1-naphthalenylamino)carbonyl]benzoic acid;

NC 310 4-(2,4-dichlorobenzoyl)-1-methyl-5-benzyloxypyrazole;

neburon 1-butyl-3-(3,4-dichlorophenyl)-1-methylurea;

nicosulfuron 2-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-N,N-dimethyl-3-pyridinecarboxamide;

nipyraclophen 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-nitropyrazole;

nitralin 4-(methylsulfonyl)-2,6-dinitro-N,N-dipropylaniline;

nitrofen 2,4-dichloro-1-(4-nitrophenoxy)benzene;

nitrofluorfen 2-chloro-1-(4-nitrophenoxy)-4-(trifluoromethyl)benzene;

norflurazon 4-chloro-5-(methylamino)-2-[3-(trifluoromethyl)phenyl]-3(2H)-pyridazinone;

orbencarb S-[2-(chlorophenyl)methyl]diethylcarbamothioate;

oryzalin 4-(dipropylamino)-3,5-dinitrobenzenesulfonamide;

oxadiazon 3-[2,4-dichloro-5-(1-methylethoxy)phenyl]-5-(1,1-dimethylethyl)-1,3, 4-oxadiazol-2(3H)-one;

oxyfluorfen 2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl)benzene;

paraquat 1,1'-dimethyl-4,4'-dipyridinium ion;

pebulate S-propyl butylethylcarbamothioate;

pendimethalin N-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzenamine;

perfluidone 1,1-trifluoro-N-[2-methyl-4-(phenylsulfonyl)phenyl]methanesulfonamide;

phenisopham 3-[[(1-methylethoxy)carbonyl]amino]phenyl ethylphenylcarbamate;

phenmedipham3-[(methoxycarbonyl)amino]phenyl (3-methylphenyl)carbamate;

piclorem 4-amino-3,5,6-trichloro-2-pyridinecarboxylic acid;

piperophos S-[2-(2-methyl-1-piperidinyl)-2-oxoethyl] O,O-dipropyl phosphorodithioate;

pirifenop-butyl butyl 2-[4-[(3,5-dichloro-2-pyridinyl)oxy]phenoxy]propanoate;

PPG-1013 methyl 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitroacetophenone oxime O-acetate;

pretilachlor 2-chloro-N-(2,6-diethylphenyl)-N-(2-propoxyethyl)acetamide;

primisulfuron-methyl methyl 2-[[[[[4,6-bis(difluoromethoxy)pyrimidin-2-yl]amino]carbonyl]amino]sulfonyl]-benzoate;

procyazine 2-[[4-chloro-6-(cyclopropylamino)-1,3,5-triazine-2-yl]amino]-2-methylpropanenitrile;

prodiamine 2,4-dinitro-N³ N³ -dipropyl-6-(trifluoromethyl)-1,3-benzenediamine;

profluralin N-(cyclopropylmethyl)-2,6-dinitro-N-propyl-4-(trifluoromethyl)benzenamine;

proglinazine-ethyl ethyl N-[4-chloro-6-[(1-methylethyl)amino]-1,3,5-triazin-2-yl]glycinate;

prometon 6-methoxy-N,N'-bis(1-methylethyl)-1,3,5-triazine-2,4-diamine;

prometryn N,N'-bis(1-methylethyl)-6-(methylthio)-1,3,5-triazine-2,4-diamine;

propachlor 2-chloro-N-(1-methylethyl)-N-phenylacetamide;

propanil N-(3,4-dichlorophenyl)propanamide;

propaquizafop 2-[[(1-methylethylidene)amino]oxy]ethyl 2-[4-[(6-chloro-2-quinoxalinyl)oxy]phenoxy]propanoate;

propazine 6-chloro-N,N'-bis(1-methylethyl)-1,3,5-triazine2,4-diamine;

propham 1-methylethyl phenylcarbamate;

propyzamide 3,5-dichloro-N-(1,1-dimethyl-2-propynyl)benzamide;

prosulfalin N-[[4-(dipropylamino)-3,5-dinitrophenyl]-sulfonyl]-S,S-dimethylsulfilimine;

prosulfocarb S-(phenyl)methyl dipropylcarbamothioate;

prynachlor 2-chloro-N-(1-methyl-2-propynyl)acetanilide;

pyrazolynate [4-(2,4-dichlorobenzoyl)-1,3-dimethylpyrazol-5-yl]toluene-4-sulfonate;

pyrazon 5-amino-4-chloro-2-phenyl-3(2H)-pyridazinone;

pyrazosulfuron-ethyl 1-(4,6-dimethoxypyrimidin-2-yl)-3 -[[(1-methyl)-4-(ethoxycarbonyl)pyrazol-5-yl]sulfonyl]urea;

pyrazoxyfen 2-[[4-(2,4-dichlorobenzoyl)-1,3-dimethyl-1H-pyrazol-5-yl]oxy]-1-phenylethanone;

pyributicarb O-[3-(1,1-dimethylethyl) phenyl](6-methoxy-2-pyridinyl) methylcarbamothioate;

pyridate O-(6-chloro-3-phenyl-4-pyridazinyl) S-octyl carbonothioate;

quinclorac 3,7-dichloro-8-quinolinecarboxylic acid;

quinmerac 7-chloro-3-methyl-8-quinolinecarboxylic acid;

quizalofop-ethyl ethyl 2-[4-[(6-chloro-2-quinoxalinyl)oxy]phenoxy]propanoate;

S 275 2-[4-chloro-2-fluoro-5-(2-propynyloxy) phenyl]-4,5,6,7-tetrahydro-2H-indazole;

S 482 2-[7-fluoro-3,4-dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione;

secbumeton N-ethyl-6-methoxy-N'-(1-methylpropyl)-1,3,5-triazine-2,4-diamine;

sethoxydim 2-[1-(ethoxyimino)butyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one;

siduron N-(2-methylcyclohexyl)-N'-phenylurea;

simazine 6-chloro-N,N'-diethyl-1,3,5-triazine-2,4-diamine;

simetryn N,N'-diethyl-6-(methylthio)-1,3,5-triazine-2,4-diamine;

SN 106279 methyl 2-[[7-[2-chloro-4-(trifluoromethyl)phenoxy]-2-naphthalenyl]oxy]propanoate;

sulfometuron-methyl methyl 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]benzoate;

TCA trichloroacetic acid;

tebutam2,2-dimethyl-N-(1-methylethyl)-N-(phenylmethyl)propanamide;

tebuthiuron N-[5-(1,1-dimethylethyl)-1,3,4-thiadiazol-2-yl]-N,N'-dimethylurea;

terbacil 5-chloro-3-(1,1-dimethylethyl)-6-methyl-2,4(1H,3H)-pyrimidinedione;

terbucarb 2,6-bis(1,1-dimethylethyl)-4-methylphenyl methylcarbamate,

terbuchlor N-(butoxymethyl)-2-chloro-N-[2-(1,1-dimethylethyl)-6-methylphenyl]acetamide;

terbumeton N-(1,1-dimethylethyl)-N'-ethyl-6-methoxy-1,3,5-triazine-2,4-diamine;

terbuthylazine 6-chloro-N-(1,1-dimethylethyl)-N'-ethyl-1,3,5-triazine-2,4-diamine;

terbutryn N-(1,1-dimethylethyl)-N'-ethyl-6-(methylthio)-1,3,5-triazine-2,4-diamine;

TFH 450 N,N-diethyl-3-[(2-ethyl-6-methylphenyl)-sulfonyl]-1H-1,2,4-triazole-1-carboxamide;

thiazafluron N,N'-dimethyl-N-[5-(trifluoromethyl)-1,3,4-thiadiazol-2-yl]-urea;

thifensulfuron-methyl methyl 3-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]thiophenecarboxylate;

thiobencarb S-[(4-chlorophenyl)-methyl]-diethylcarbamothioate;

tiocarbazil S-(phenylmethyi)-bis(1-methylpropyl)carbamothioate;

tralkoxydim 2-[1-(ethoxyimino)propyl]-5-[2,4,6-trimethylphenyl]-3-hydroxy-2-cyclohexen-1-one;

tri-allate S-(2,3,3-trichloro-2-propenyl) bis(1-methylethyl)carbamothioate;

triasulfuron 1-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-3-[2-(2-chloroethoxy)phenylsulfonyl]urea;

triazofenamide 1-(3-methylphenyl)-5-phenyl-1,2,4-triazole-2-carboxamide;

tribenuron-methyl methyl 2-[[[N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N-methylamino]carbonyl]amino]sulfonyl]benzoate;

triclopyr [(3,5,6-trichloro-2-pyridinyl)oxy]acetic acid;

tridiphane 2-(3,5-dichlorophenyl)-2-(2,2,2-trichloroethyl)oxirane;

trietazine 6-chloro-N,N,N'-triethyl-1,3,5-triazine-2,4-diamine;

trifluralin 2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzenamine;

trimeturon 1-(4-chlorophenyl)-2,3,3-trimethylpseudourea;

vernolate S-propyl dipropylcarbamothioate;

WL 110547 5-phenoxy-1-[3-(trifluoromethyl)phenyl]-1H-tetrazole.

The active substance content of the use forms of the active substances can vary within wide ranges, for example from 0.0001 to 100% by weight of active substance, preferably 0.001 to 99% by weight of active substance.

The agrochemical preparations (formulations) generally contain 0.1 to 99 percent by weight, in particular 0.1 to 95% by weight, of herbicidal active substance, and 1 to 99.9% by weight, preferably 5 to 99.9% by weight, of formulation auxiliaries which are inert under the storage and use conditions.

The preparations are applied in a customary manner which suits the use forms.

For example, the formulations, present in commercially available form, are diluted for use, if appropriate, in a conventional manner, for example using water in the case of wettable powders, emulsifiable concentrates, dispersions and water-dispersible granules. Preparations in the form of dusts and granules and also sprayable solutions are usually not further diluted with other inert substances before use.

The required application rate of the compounds of the formula (I) according to the invention varies with the external conditions such as, inter alia, temperature, humidity, and nature of the herbicide used. It can be varied within wide limits, for example between 0.001 and 10.0 kg/ha or more of active ingredient, but it is preferably between 0.005 and 5 kg/ha.

A. Chemical Examples Example 1: N-tert. -butyl- (2-iodo-3-methoxycarbonyl)benzenesulfonamide

A solution of 24.1 g of tert.-butylamine in 30 ml of dichloromethane is added dropwise at room temperature to 59.3 g of 2-iodo-3-methoxycarbonylbenzenesulfochloride in 300 ml of dichloromethane. Stirring is continued for 3 hours at room temperature, the mixture is washed with 2N hydrochloric acid and dried over Na₂ SO₄, and the solvent is evaporated. The residue is digested in ether. This gives 30.0 g of N-tert.-butyl-(2-iodo-3-methoxycarbonyl)benzenesulfonamide in the form of colorless-crystals of m.p. 148°-9° C.

Example 2: 2-Iodo-3-methoxycarbonylbenzenesulfonamide

27.9 g of N-tert.-butyl-(2-iodo-3-methoxycarbonyl)benzene-sulfonamide are stirred with 100 ml of trifluoroacetic acid for 4 hours at room temperature, the mixture is heated for 2 hours at the boil, and the organic phase is then evaporated in vacuo. The residue is taken up in dichloromethane/water, and sodium carbonate is added until the reaction is neutral. The phases are separated, and the aqueous phase is extracted two more times using dichloromethane. The combined organic phases are dried over Na₂ SO₄, and the solvent is evaporated. After stirring of the residue with ether, 17.4 g of 2-iodo-3-methoxycarbonylbenzenesulfonamide of m.p. 155°-7° C. are obtained.

Example 3: Methyl 2-amino-4-iodobenzoate

A solution of 16.1 g of 2-acetylamino-4-iodobenzoic acid (m.p. 233°-5° C.; synthesized in accordance with U.S. Pat. No. 4,762,838) in 325 ml of absolute methanol is saturated at 0° C. with dry hydrogen chloride gas. The mixture is heated to the boil for 15 hours, cooled to room temperature, resaturated using dry hydrogen chloride gas, and allowed to stand at room temperature for 24 hours. The solvent is evaporated in vacuo, the residue is taken up in dichloromethane, and the organic phase is washed with a saturated aqueous sodium hydrogen carbonate solution until free from acid. The organic phase is dried over Na₂ SO₄, and evaporated in vacuo. This gives 13.8 g of methyl 2-amino-4-iodobenzoate of m.p. 63°-7° C.

Example 4: Bis (2-methoxycarbonyl-5-iodobenzene)disulfide

13.8 g of methyl 2-amino-4-iodobenzoate are treated with 48 ml of glacial acetic acid and subsequently with 86 ml of concentrated hydrochloric acid. A solution of 3.8 g of sodium nitrite in 15 ml of water is slowly added dropwise to this suspension which is cooled to -5° C., and stirring is continued at this temperature for 30 minutes. This cooled diazonium salt solution is added dropwise at 0° C. to a solution of 20 ml of sulfur dioxide, 60 ml of glacial acetic acid, 10 ml of water and 3.1 g of copper(II) chloride dihydrate, and stirring is continued first for 1 hour at 0° C. and then overnight at room temperature. The reaction mixture is poured into 1 l of ice-water, and the product is filtered off with suction. This gives 12.7 g of bis(2-methoxycarbonyl-5-iodobenzene)disulfide of m.p. 133°-5° C.

Example 5: 2-Methoxycarbonyl-5-iodobenzenesulfochloride

Chlorine gas is passed at 20°-25° C. into 12.2 g of bis(2-methoxycarbonyl-5-iodobenzene)disulfide in a solution of 30 ml of 1,2-dichloroethane and 15 ml of 2N hydrochloric acid until the exothermic reaction has ended. The solids are filtered off with suction, the aqueous phase is extracted using dichloromethane, the combined organic phases are dried over Na₂ SO₄, and the solvent is evaporated in vacuo. This gives a total amount of 15.0 g of 2-methoxycarbonyl-5-iodobenzenesulfochloride, from the filtered and extracted product, of m.p. 119°-120° C. (decomposition).

Example 6: 2-Methoxycarbonyl-5-iodobenzenesulfonamide

Ammonia gas is passed at room temperature into 15.0 g of 2-methoxycarbonyl-5-iodobenzenesulfochloride in 100 ml of tetrahydrofuran until ammonia is no longer taken up. The solution is evaporated in vacuo, the residue is stirred thoroughly with water, and the product is filtered off with suction. After drying of the filter residue at 70° C. in vacuo, 10.7 g of 2-methoxycarbonyl-5-iodobenzenesulfonamide are obtained as a white powder of m.p. 176°-7° C.

Example 7: 3-Ethoxycarbonyl- 2- iodobenzenesulfochloride

24.0 g of ethyl 3-amino-2-iodobenzoate are dissolved in 60 ml of glacial acetic acid and 120 ml of concentrated hydrochloric acid. A solution of 6.9 g of sodium nitrite in 30 ml of water is slowly added dropwise to this suspension which is cooled to -5° C. and stirring is continued at this temperature for 30 minutes. This cooled diazonium salt solution is added dropwise at 5°-10° C. to a solution of 70 ml of glacial acetic acid, 70 ml of concentrated hydrochloric acid and 3.0 g of copper(II) chloride dihydrate, which has been saturated with sulfur dioxide at approx. 10° C. The mixture is stirred for 3 hours at room temperature, and chlorine gas is then passed in until the exothermic reaction subsides. The reaction mixture is poured into 1 l of ice-water, and the product is filtered off with suction and dried in vacuo at 50° C. This gives 25.3 g of 3 -ethoxycarbonyl-2-iodobenzenesulfo-chloride of m.p. 80°-3° C.

Example 8: 3-Ethoxycarbonyl-2-iodobenzenesulfonamide

Analogously to Example 6, 25.3 g of 3-ethoxycarbonyl-2-iodobenzenesulfochloride and ammonia gave 20.4 g of 3-ethoxycarbonyl-2-iodobenzenesulfonamide of m.p. 138°-9° C.

Example 9: Methyl 2-[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-4-iodobenzoate

A solution of 1.7 g of 1,8-diazabicyclo[5.4.0]undec-7-ene in 10 ml of absolute acetonitrile is added dropwise at room temperature to a mixture of 3.4 g of 5-iodo-2-methoxycarbonylbenzenesulfonamide and 2.8 g of O-phenyl (4,6-dimethoxy-2-pyrimidinyl)carbamate in 50 ml of absolute acetonitrile. The mixture is stirred at this temperature for 3 hours, concentrated to approx. 1/3 and poured into 200 ml of ice-water. The aqueous phase is extracted using diethyl ether, the pH is brought to 1-2 using concentrated hydrochloric acid, and the product is filtered off with suction. After drying in vacuo at 60° C., 3.3 g of methyl 2-[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-4-iodobenzoate of m.p. 169°-71° C. are obtained.

Example 10: Ethyl 2-iodo-3-[[[[(4-methoxy-6-methyl-1,3,5-triazin- 2-yl)amino]carbonyl]amino]sulfonyl]benzoate

14 mmol of trimethylaluminum (7 ml of a 2M solution in hexane) are added dropwise under a nitrogen protective atmosphere to a suspension of 3.6 g of 3-ethoxycarbonyl-2-iodobenzenesulfonamide in 100 ml of absolute dichloromethane. The mixture is stirred at room temperature for 30 minutes, and 2.2 g of O-methyl (4-methyl-6-methoxy-1,3,5-triazin-2-yl)carbamate in 25 ml of dichloromethane are then added, and the mixture is refluxed for 13 hours. The solution is cooled to room temperature, 25 ml of 2N hydrochloric acid are added dropwise with ice-cooling, and the hydrochloric acid phase is extracted twice using dichloromethane. The organic phase is concentrated in vacuo, and the residue is treated with acetone and 100 ml of 10% aqueous sodium acetate solution. The mixture is stirred for 3 hours and then filtered off with suction, followed by a washing step with diethyl ether, the aqueous phase is brought to pH 2-3 using concentrated hydrochloric acid and stirred for 15 minutes, and the product is filtered off with suction. After drying in vacuo at 50° C., 1.7 g of ethyl 2-iodo-3-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]-benzoate of m.p. 177°-9° C. are obtained.

Example 11: 2-Methoxycarbonyl-5-iodobenzenesulfonyl isocyanate

50 g of the sulfonamide obtained in Example 6 are suspended in 150 ml of 1,2-dichloroethane and the suspension is treated with 27.7 ml of thionyl chloride. The mixture is heated at the boil for 4 hours, cooled to 50°-55° C. and treated with 0.5 ml of pyridine, and phosgene is passed for 31/2 hours into the solution which has now been brought to the boil. The mixture is concentrated under reduced pressure with the exclusion of moisture. The crude sulfonyl isocyanate which remains (52.6 g) crystallises upon standing.

Example 12: 2-Iodo-3-methoxycarbonylbenzenesulfonyl isocyanate

27.3 g of 2-iodo-3-methoxycarbonylbenzenesulfonamide and 9.0 ml of n-butyl isocyanate in 300 ml of absolute acetone are treated with 12 ml of DBU at room temperature and heated at the boil for 3 hours. The reaction solution is cooled to room temperature, concentrated to approximately 1/3 of its volume and poured into 1 l of water. The aqueous phase is acidified with concentrated hydrochloric acid to a pH of 1-2, and the precipitate obtained is filtered off with suction. 31.3 g of methyl 2-iodo-[[[(n-butylamino)carbonyl]amino]sulfonyl]benzoate of melting point 163°-7° C. are obtained.

29.0 g of the resulting butylsulfonylurea are suspended in 400 ml of chlorobenzene and the suspension is brought to the boil. Phosgene is then passed in at boiling heat. The resulting butyl isocyanate is distilled off slowly in the course of 5 hours over a 20 cm Vigreux column in the form of a mixture with chlorobenzene. The mixture is concentrated in vacuo with the exclusion of moisture. This gives 28.4 g of 2-iodo-3-methoxycarbonylbenzenesulfonyl isocyanate in the form of an oil.

The sulfonamides of Tables 1a and 1b are obtained analogously to the processes of Examples 1 to 8.

The sulfonylureas of Tables 2-6 are obtained analogously to the processes of Examples 9 and 10. In the tables, the abbreviations refer to the general formula which precedes each table.

The sulfonyl isocyanates of Tables 1c and 1d are obtained analogously to the processes of Examples 11 and 12.

                  TABLE 1a                                                         ______________________________________                                          ##STR14##                    (IIa)                                            IIa    Q       R              I    M.p. [°C.]                           ______________________________________                                         a      O       CH.sub.3       2-I  155-7                                       b      O       CH.sub.2 CH.sub.3                                                                             2-I  138-9                                       c      O       CH.sub.2 CH.sub.2 CH.sub.3                                                                    2-I  130-1                                       d      O       CH(CH.sub.3).sub.2                                                                            2-I  133                                         e      O       CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                           2-I                                              f      O       CH.sub.2 CH(CH.sub.3).sub.2                                                                   2-I                                              g      O       CH(CH.sub.3)CH.sub.2 CH.sub.3                                                                 2-I                                              h      O       C(CH.sub.3).sub.3                                                                             2-I                                              i      O       CH.sub.2 CHCH.sub.2                                                                           2-I                                              j      O       CH.sub.2 CCH   2-I                                              k      O       CH.sub.2 CH.sub.2 Cl                                                                          2-I                                              l      O       CH.sub.2 CH.sub.2 OCH.sub.3                                                                   2-I                                              m      O       c-C.sub.6 H.sub.11                                                                            2-I                                              n      O       CH.sub.3       6-I  161-2                                       o      O       CH.sub.2 CH.sub.3                                                                             6-I                                              p      O       CH.sub.2 CH.sub.2 CH.sub.3                                                                    6-I                                              q      O       CH(CH.sub.3).sub.2                                                                            6-I                                              r      O       CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                           6-I                                              s      O       CH.sub.2 CH(CH.sub.3).sub.2                                                                   6-I                                              t      O       CH(CH.sub.3)CH.sub.2 CH.sub.3                                                                 6-I                                              u      O       C(CH.sub.3).sub.3                                                                             6-I                                              v      O       CH.sub.2 CHCH.sub.2                                                                           6-I                                              w      O       CH.sub.2 CCH   6-I                                              x      O       CH.sub.2 CH.sub.2 Cl                                                                          6-I                                              y      O       CH.sub.2 CH.sub.2 OCH.sub.3                                                                   6-I                                              z      O       c-C.sub.6 H.sub.11                                                                            6-I                                              ______________________________________                                    

                  TABLE 1b                                                         ______________________________________                                          ##STR15##                    (IIb)                                            IIb    Q       R              I    M.p. [°C.]                           ______________________________________                                         a      O       CH.sub.3       3-I  194-6                                       b      O       CH.sub.2 CH.sub.3                                                                             3-I                                              c      O       CH.sub.2 CH.sub.2 CH.sub.3                                                                    3-I                                              d      O       CH(CH.sub.3).sub.2                                                                            3-I                                              e      O       CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                           3-I                                              f      O       CH.sub.2 CH(CH.sub.3).sub.2                                                                   3-I                                              g      O       CH(CH.sub.3)CH.sub.2 CH.sub.3                                                                 3-I                                              h      O       C(CH.sub.3).sub.3                                                                             3-I                                              i      O       CH.sub.2 CHCH.sub.2                                                                           3-I                                              j      O       CH.sub.2 CHCH  3-I                                              k      O       CH.sub.2 CH.sub.2 Cl                                                                          3-I                                              l      O       CH.sub.2 CH.sub.2 OCH.sub.3                                                                   3-I                                              m      O       c-C.sub.6 H.sub.11                                                                            3-I                                              n      O       CH.sub.3       5-I  181-182                                     o      O       CH.sub.2 CH.sub.3                                                                             5-I  162                                         p      O       CH.sub.2 CH.sub.2 CH.sub.3                                                                    5-I                                              q      O       CH(CH.sub.3).sub.2                                                                            5-I  139                                         r      O       CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                           5-I                                              s      O       CH.sub.2 CH(CH.sub.3).sub.2                                                                   5-I                                              t      O       CH(CH.sub.3)CH.sub.2 CH.sub.3                                                                 5-I                                              u      O       C(CH.sub.3).sub.3                                                                             5-I                                              v      O       CH.sub.2 CHCH.sub.2                                                                           5-I                                              w      O       CH.sub.2 CHCH  5-I                                              x      O       CH.sub.2 CH.sub.2 Cl                                                                          5-I                                              y      O       CH.sub.2 CH.sub.2 OCH.sub.3                                                                   5-I                                              z      O       c-C.sub.6 H.sub.11                                                                            5-I                                              aa     O       CH.sub.3       6-I  213-5                                       ab     O       CH.sub.2 CH.sub.3                                                                             6-I                                              ac     O       CH.sub.2 CH.sub.2 CH.sub.3                                                                    6-I                                              ad     O       CH(CH.sub.3).sub.2                                                                            6-I                                              ae     O       CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                           6-I                                              af     O       CH.sub.2 CH(CH.sub.3).sub.2                                                                   6-I                                              ag     O       CH(CH.sub.3)CH.sub.2 CH.sub.3                                                                 6-I                                              ah     O       C(CH.sub.3).sub.3                                                                             6-I                                              ai     O       CH.sub.2 CHCH.sub.2                                                                           6-I                                              aj     O       CH.sub.2 CHCH  6-I                                              ak     O       CH.sub.2 CH.sub.2 Cl                                                                          6-I                                              al     O       CH.sub.2 CH.sub.2 OCH.sub.3                                                                   6-I                                              am     O       c-C.sub.6 H.sub.11                                                                            6-I                                              ______________________________________                                    

                  TABLE 1c                                                         ______________________________________                                          ##STR16##                   (VIa)                                             (VIa) Q      R              I    IR band [cm.sup.-1 ]                          ______________________________________                                         a     O      CH.sub.3       3-I  2225                                          b     O      CH.sub.2 CH.sub.3                                                                             3-I  2230                                          c     O      CH.sub.2 CH.sub.2 CH.sub.3                                                                    3-I  2225                                          d     O      CH(CH.sub.3).sub.2                                                                            3-I  2225                                          e     O      CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                           3-I                                                f     O      CH.sub.2 CH(CH.sub.3).sub.2                                                                   3-I                                                g     O      CH(CH.sub.3)CH.sub.2 CH.sub.3                                                                 3-I                                                h     O      C(CH.sub.3).sub.3                                                                             3-I                                                i     O      CH.sub.2 CHCH.sub.2                                                                           3-I                                                j     O      CH.sub.2 CCH   3-I                                                k     O      CH.sub.2 CH.sub.2 Cl                                                                          3-I                                                l     O      CH.sub.2 CH.sub.2 OCH.sub.3                                                                   3-I                                                m     O      c-C.sub.6 H.sub.11                                                                            3-I                                                n     O      CH.sub.3       5-I  2225                                          o     O      CH.sub.2 CH.sub.3                                                                             5-I                                                p     O      CH.sub.2 CH.sub.2 CH.sub.3                                                                    5-I                                                q     O      CH(CH.sub.3).sub.2                                                                            5-I                                                r     O      CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                           5-I                                                s     O      CH.sub.2 CH(CH.sub.3).sub.2                                                                   5-I                                                t     O      CH(CH.sub.3)CH.sub.2 CH.sub.3                                                                 5-I                                                u     O      C(CH.sub.3).sub.3                                                                             5-I                                                v     O      CH.sub.2 CHCH.sub.2                                                                           5-I                                                w     O      CH.sub.2 CCH   5-I                                                x     O      CH.sub.2 CH.sub.2 Cl                                                                          5-I                                                y     O      CH.sub.2 CH.sub.2 OCH.sub.3                                                                   5-I                                                z     O      c-C.sub.6 H.sub.11                                                                            5-I                                                aa    O      CH.sub.3       6-I                                                ab    O      CH.sub.2 CH.sub.3                                                                             6-I                                                ac    O      CH.sub.2 CH.sub.2 CH.sub.3                                                                    6-I                                                ad    O      CH(CH.sub.3).sub.2                                                                            6-I                                                ae    O      CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                           6-I                                                af    O      CH.sub.2 CH(CH.sub.3).sub.2                                                                   6-I                                                ag    O      CH(CH.sub.3)CH.sub.2 CH.sub.3                                                                 6-I                                                ah    O      C(CH.sub.3).sub.3                                                                             6-I                                                ai    O      CH.sub.2 CHCH.sub.2                                                                           6-I                                                aj    O      CH.sub.2 CCH   6-I                                                ak    O      CH.sub.2 CH.sub.2 Cl                                                                          6-I                                                al    O      CH.sub.2 CH.sub.2 OCH.sub.3                                                                   6-I                                                am    O      c-C.sub.6 H.sub.11                                                                            6-I                                                ______________________________________                                    

                  TABLE 1d                                                         ______________________________________                                          ##STR17##                   (VIb)                                             (VIb) Q      R              I    IR band [cm.sup.-1 ]                          ______________________________________                                         a     O      CH.sub.3       3-I  2230                                          b     O      CH.sub.2 CH.sub.3                                                                             3-I                                                c     O      CH.sub.2 CH.sub.2 CH.sub.3                                                                    3-I                                                d     O      CH(CH.sub.3).sub.2                                                                            3-I                                                e     O      CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                           3-I                                                f     O      CH.sub.2 CH(CH.sub.3).sub.2                                                                   3-I                                                g     O      CH(CH.sub.3)CH.sub.2 CH.sub.3                                                                 3-I                                                h     O      C(CH.sub.3).sub.3                                                                             3-I                                                i     O      CH.sub.2 CHCH.sub.2                                                                           3-I                                                j     O      CH.sub.2 CCH   3-I                                                k     O      CH.sub.2 CH.sub.2 Cl                                                                          3-I                                                l     O      CH.sub.2 CH.sub.2 OCH.sub.3                                                                   3-I                                                m     O      c-C.sub.6 H.sub.11                                                                            3-I                                                n     O      CH.sub.3       5-I  2230                                          o     O      CH.sub.2 CH.sub.3                                                                             5-I  2225                                          p     O      CH.sub.2 CH.sub.2 CH.sub. 3                                                                   5-I                                                q     O      CH(CH.sub.3).sub.2                                                                            5-I  2225                                          r     O      CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                           5-I                                                s     O      CH.sub.2 CH(CH.sub.3).sub.2                                                                   5-I                                                t     O      CH(CH.sub.3)CH.sub.2 CH.sub.3                                                                 5-I                                                u     O      C(CH.sub.3).sub.3                                                                             5-I                                                v     O      CH.sub.2 CHCH.sub.2                                                                           5-I                                                w     O      CH.sub.2 CCH   5-I                                                x     O      CH.sub.2 CH.sub.2 Cl                                                                          5-I                                                y     O      CH.sub.2 CH.sub.2 OCH.sub.3                                                                   5-I                                                z     O      c-C.sub.6 H.sub.11                                                                            5-I                                                aa    O      CH.sub.3       6-I  222-5                                         ab    O      CH.sub.2 CH.sub.3                                                                             6-I                                                ac    O      CH.sub.2 CH.sub.2 CH.sub.3                                                                    6-I                                                ad    O      CH(CH.sub.3).sub.2                                                                            6-I                                                ae    O      CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                                                           6-I                                                af    O      CH.sub.2 CH(CH.sub.3).sub.2                                                                   6-I                                                ag    O      CH(CH.sub.3)CH.sub.2 CH.sub.3                                                                 6-I                                                ah    O      C(CH.sub.3).sub.3                                                                             6-I                                                ai    O      CH.sub.2 CHCH.sub.2                                                                           6-I                                                aj    O      CH.sub.2 CCH   6-I                                                ak    O      CH.sub.2 CH.sub.2 Cl                                                                          6-I                                                al    O      CH.sub.2 CH.sub.2 OCH.sub.3                                                                   6-I                                                am    O      c-C.sub.6 H.sub.11                                                                            6-I                                                ______________________________________                                    

                                      TABLE 2                                      __________________________________________________________________________      ##STR18##                                                                     Ex.                                  M.p.                                      No. Q R        R.sup.1                                                                           R.sup.2                                                                              R.sup.3                                                                              W Y  Z [°C.]                              __________________________________________________________________________     1   O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N 216-7                                     2   O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N 181-2                                     3   O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N 133-4                                     4   O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N 210                                       5   O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N 201-2                                     6   O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           7   O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N 196 decomp.                               8   O CH.sub.3 R  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N 205-6                                     9   O CH.sub.3 H  OCH.sub.3                                                                            Cl    O CH N 218-21                                    10  O CH.sub.3 H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           11  O CH.sub.3 H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N 192-3                                     12  O CH.sub.3 H  OCH.sub.3                                                                            Br    O CH N                                           13  O CH.sub.3 H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           14  O CH.sub.3 H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           15  O CH.sub.3 H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           16  O CH.sub.3 H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           17  O CH.sub.3 H  OCH.sub.3                                                                            Cl    O N  N                                           18  O CH.sub.3 H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           19  O CH.sub.3 H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           20  O CH.sub.3 H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           21  O CH.sub.3 H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           22  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           23  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           24  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           25  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           26  O CH.sub.3 H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           27  O CH.sub.3 H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           28  O CH.sub.3 H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           29  O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           30  O CH.sub.3 H  Cl    CH.sub.3                                                                             O N  N                                           31  O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           32  O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           33  O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           34  O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           35  O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           36  O CH.sub.3 R  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           37  O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           38  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           39  O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           40  O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           41  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           42  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           43  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           44  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           45  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           46  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            Cl    O CH N                                           47  O C.sub.2 H.sub.5                                                                         H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           48  O C.sub.2 H.sub.5                                                                         H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           49  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            Br    O CH N                                           50  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           51  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           52  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           53  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           54  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            Cl    O N  N                                           55  O C.sub.2 H.sub.5                                                                         H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           56  O C.sub.2 H.sub.5                                                                         H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           57  O C.sub.2 H.sub.5                                                                         H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           58  O C.sub.2 H.sub.5                                                                         H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           59  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           60  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           61  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           62  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           63  O C.sub.2 H.sub. 5                                                                        H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           64  O C.sub.2 H.sub.5                                                                         H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           65  O C.sub.2 H.sub.5                                                                         H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           66  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           67  O C.sub.2 H.sub.5                                                                         H  Cl    CH.sub.3                                                                             O N  N                                           68  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           69  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           70  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           71  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           72  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           73  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           74  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           75  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           76  O n-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           77  O n-C.sub. 3 H.sub.7                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           78  O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           79  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           80  O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           81  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           82  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           83  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O CH N                                           84  O n-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           85  O n-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           86  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Br    O CH N                                           87  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           88  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           89  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           90  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           91  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O N  N                                           92  O n-C.sub.3 H.sub.7                                                                       H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           93  O n-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           94  O n-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           95  O n-C.sub.3 H.sub.7                                                                       H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           96  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           97  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           98  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           99  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           100 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           101 O n-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           102 O n-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           103 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           104 O n-C.sub.3 H.sub.7                                                                       H  Cl    CH.sub.3                                                                             O N  N                                           105 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           106 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           107 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           108 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           109 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           110 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           111 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           112 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           113 O i-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           114 O i-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           115 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           116 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           117 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           118 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           119 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           120 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O CH N                                           121 O i-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           122 O i-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           123 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Br    O CH N                                           124 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           125 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           126 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           127 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           128 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O N  N                                           129 O i-C.sub.3 H.sub.7                                                                       H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           130 O i-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           131 O i-C.sub.3 H.sub. 7                                                                      H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           132 O i-C.sub.3 H.sub.7                                                                       H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           133 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           134 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           135 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           136 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           137 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           138 O i-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           139 O i-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           140 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           141 O i-C.sub.3 H.sub.7                                                                       H  Cl    CH.sub.3                                                                             O N  N                                           142 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           143 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           144 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           145 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           146 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           147 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           148 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           149 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           150 O CH.sub.2 CHCH.sub.2                                                                     CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           151 O CH.sub.2 CHCH.sub.2                                                                     CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           152 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           153 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           154 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           155 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           156 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           157 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            Cl    O CH N                                           158 O CH.sub.2 CHCH.sub.2                                                                     H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           159 O CH.sub.2 CHCH.sub.2                                                                     H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           160 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            Br    O CH N                                           161 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           162 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           163 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           164 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           165 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            Cl    O N  N                                           166 O CH.sub.2 CHCH.sub.2                                                                     H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           167 O CH.sub.2 CHCH.sub.2                                                                     H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           168 O CH.sub.2 CHCH.sub.2                                                                     H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           169 O CH.sub.2 CHCH.sub.2                                                                     H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           170 O CH.sub.2 CHCH.sub. 2                                                                    H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           171 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           172 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           173 O CH.sub.2 CHCH.sub.2                                                                     R  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           174 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           175 O CH.sub.2 CHCH.sub.2                                                                     H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           176 O CH.sub.2 CHCH.sub.2                                                                     H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           177 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           178 O CH.sub.2 CHCH.sub.2                                                                     H  Cl    CH.sub.3                                                                             O N  N                                           179 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           180 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           181 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           182 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub. 3                                                                            S N  N                                           184 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           185 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           186 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           187 O CH.sub.2 CCH                                                                            CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           188 O CH.sub.2 CCH                                                                            CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           189 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           190 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           191 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           192 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           193 O CH.sub. 2 CCH                                                                           H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           194 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            Cl    O CH N                                           195 O CH.sub.2 CCH                                                                            H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           196 O CH.sub.2 CCH                                                                            H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           197 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            Br    O CH N                                           198 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           199 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           200 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           201 O CH.sub.2 C CH                                                                           H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           202 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            Cl    O N  N                                           203 O CH.sub.2 CCH                                                                            H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           204 O CH.sub.2 CCH                                                                            H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           205 O CH.sub.2 CCH                                                                            H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           206 O CH.sub.2 CCH                                                                            H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           207 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           208 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           209 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           210 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           211 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           212 O CH.sub.2 CCH                                                                            H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           213 O CH.sub.2 CCH                                                                            H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           214 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           215 O CH.sub.2 CCH                                                                            H  Cl    CH.sub.3                                                                             O N  N                                           216 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           217 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           218 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           219 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           220 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           221 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           222 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           223 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           224 O n-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           225 O n-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           226 O n-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           227 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           228 O n-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           229 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           230 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           231 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           232 O i-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           233 O i-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           234 O i-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           235 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           236 O i-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           237 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           238 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           239 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           240 O sec.-C.sub.4 H.sub.9                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           241 O sec.-C.sub.4 H.sub.9                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           242 O sec.-C.sub.4 H.sub.9                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           243 O Sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           244 O sec.-C.sub.4 H.sub.9                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           245 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           246 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           247 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           248 O t-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           249 O t-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           250 O t-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           251 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           252 O t-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           253 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           254 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           255 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           256 O CH.sub.2 CH.sub.2 Cl                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           257 O CH.sub.2 CH.sub.2 Cl                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           258 O CH.sub.2 CH.sub.2 Cl                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           259 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           260 O CH.sub.2 CH.sub.2 Cl                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           261 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           262 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           263 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           264 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           265 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           266 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           267 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           268 O C.sub.2 CH.sub.2 OCH.sub.3                                                              H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           269 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           270 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           271 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           272 O c-C.sub.6 H.sub.11                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           273 O c-C.sub.6 H.sub.11                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           274 O c-C.sub.6 H.sub.11                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           275 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           276 O c-C.sub.6 H.sub.11                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           277 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           278 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           279 O CH.sub.3 H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N 211-3 decomp.                             280 O CH.sub.3 H  CH.sub.3                                                                             SCH.sub.3                                                                            O N  N 196-8                                     281 O CH.sub.3 H  c-C.sub.3 H.sub.5                                                                    OCH.sub.3                                                                            O N  N 175-8                                     282 O CH.sub.3 H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O N  N 195-6                                     283 O CH.sub.3 H  CH.sub.2 SCH.sub.3                                                                   OCH.sub.3                                                                            O N  N 147-50                                    284 O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N 131-3                                     285 O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N Na-salt                                                                        189                                       286 O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N Na-salt                                                                        195                                       287 O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N Na-salt                                                                        189                                       288 O CH.sub.3 H  c-C.sub.3 H.sub.5                                                                    CH.sub.3                                                                             O N  N Na-salt                                                                        170                                       289 O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N Na-salt                                                                        130                                       290 O CH.sub.3 H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O N  N Na-salt                                                                        172                                       291 O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N Li-salt                                                                        124                                       292 O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N Na-salt                                                                        191                                       293 O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N Na-salt                                                                        118                                       294 O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N Na-salt                                                                        138                                       295 O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N Na-salt                                                                        184                                       __________________________________________________________________________

                                      TABLE 3                                      __________________________________________________________________________      ##STR19##                                                                     Ex.                                      M.p.                                  No. Q R        R.sup.1                                                                           R.sup.2  R.sup.3                                                                               W Y  Z [°C.]                          __________________________________________________________________________     1   O CH.sub.3 H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N 169-71                                2   O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N 186-7                                 3   O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N 172-3                                 4   O CH.sub.3 H  CH.sub.3 CH.sub.3                                                                              O CH N 195-6                                 5   O CH.sub.3 H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N 177                                   6   O CH.sub.3 H  CH.sub.3 CH.sub.3                                                                              O N  N 182-4                                 7   O CH.sub.3 H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N 158-63                                8   O CH.sub.3 H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N 174                                   9   O CH.sub.3 H  OCH.sub.3                                                                               Cl     O CH N 170-2                                 10  O CH.sub.3 H  OCF.sub.2 H                                                                             CH.sub.3                                                                              O CH N                                       11  O CH.sub.3 H  OCF.sub.2 H                                                                             OCF.sub.2 H                                                                           O CH N 178-9                                 12  O CH.sub.3 H  OCH.sub.3                                                                               Br     O CH N                                       13  O CH.sub.3 H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O CH N                                       14  O CH.sub.3 H  OCH.sub.3                                                                               SCH.sub.3                                                                             O CH N                                       15  O CH.sub.3 H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O N  N                                       16  O CH.sub.3 H  OCH.sub.3                                                                               OC.sub.3 H.sub.7                                                                      O CH N                                       17  O CH.sub.3 H  OCH.sub.3                                                                               Cl     O N  N                                       18  O CH.sub.3 H  Cl       OC.sub.2 H.sub.5                                                                      O CH N                                       19  O CH.sub.3 H  OC.sub.2 H.sub.5                                                                        OC.sub.2 H.sub.5                                                                      O CH N                                       20  O CH.sub.3 H  C.sub.2 H.sub.5                                                                         OCH.sub.3                                                                             O CH N                                       21  O CH.sub.3 H  CF.sub.3 OCH.sub.3                                                                             O CH N                                       22  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                      CH.sub.3                                                                              O CH N                                       23  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O CH N                                       24  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.2 CF.sub.3                                                                    O CH N                                       25  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O N  N 125 decomp.                           26  O CH.sub.3 H  OCH.sub.3                                                                               NHCH.sub.3                                                                            O N  N                                       27  O CH.sub.3 H  OC.sub.2 H.sub.5                                                                        NHCH.sub.3                                                                            O N  N                                       28  O CH.sub.3 H  C.sub.2 H.sub.5                                                                         OC.sub.2 H.sub.5                                                                      O N  N                                       29  O CH.sub.3 H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       30  O CH.sub.3 H  Cl       CH.sub.3                                                                              O N  N                                       31  O CH.sub.3 H  CH.sub.3 CH.sub.3                                                                              O N  N                                       32  O CH.sub.3 H  OCH.sub.3                                                                               OCH.sub.3                                                                             S CH N                                       33  O CH.sub.3 H  OCH.sub.3                                                                               CH.sub.3                                                                              S CH N                                       34  O CH.sub.3 H  CH.sub.3 CH.sub.3                                                                              S CH N                                       35  O CH.sub.3 H  OCH.sub.3                                                                               OCH.sub.3                                                                             S N  N                                       36  O CH.sub. 3                                                                               H  OCH.sub.3                                                                               CH.sub.3                                                                              S N  N                                       37  O CH.sub.3 H  CH.sub.3 CH.sub.3                                                                              S N  N                                       38  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N 174-7                                 39  O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N 155-7                                 40  O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N 163-4                                 41  O C.sub.2 H.sub.5                                                                         H  CH.sub.3 CH.sub.3                                                                              O CH N                                       42  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N 183-4                                 43  O C.sub.2 H.sub.5                                                                         H  CH.sub.3 CH.sub.3                                                                              O N  N                                       44  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N 168-70                                45  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N 154-8                                 46  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               Cl     O CH N 151-3                                 47  O C.sub.2 H.sub.5                                                                         H  OCF.sub.2 H                                                                             CH.sub.3                                                                              O CH N                                       48  O C.sub.2 H.sub.5                                                                         H  OCF.sub.2 H                                                                             OCF.sub.2 H                                                                           O CH N                                       49  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               Br     O CH N                                       50  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O CH N                                       51  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               SCH.sub.3                                                                             O CH N                                       52  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O N  N                                       53  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               OC.sub.3 H.sub.7                                                                      O CH N                                       54  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               Cl     O N  N                                       55  O C.sub.2 H.sub.5                                                                         H  Cl       OC.sub.2 H.sub.5                                                                      O CH N                                       56  O C.sub.2 H.sub.5                                                                         H  OC.sub.2 H.sub.5                                                                        OC.sub.2 H.sub.5                                                                      O CH N                                       57  O C.sub.2 H.sub.5                                                                         H  C.sub.2 H.sub.5                                                                         OCH.sub.3                                                                             O CH N                                       58  O C.sub.2 H.sub.5                                                                         H  CF.sub.3 OCH.sub.3                                                                             O CH N                                       59  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                      CH.sub.3                                                                              O CH N                                       60  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O CH N                                       61  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.2 CF.sub.3                                                                    O CH N                                       62  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O N  N                                       63  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               NHCH.sub.3                                                                            O N  N                                       64  O C.sub.2 H.sub.5                                                                         H  OC.sub.2 H.sub.5                                                                        NHCH.sub.3                                                                            O N  N                                       65  O C.sub.2 H.sub.5                                                                         H  C.sub.2 H.sub.5                                                                         OC.sub.2 H.sub.5                                                                      O N  N                                       66  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       67  O C.sub.2 H.sub.5                                                                         H  Cl       CH.sub.3                                                                              O N  N                                       68  O C.sub.2 H.sub.5                                                                         H  CH.sub.3 CH.sub.3                                                                              O N  N                                       69  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               OCH.sub.3                                                                             S CH N                                       70  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               CH.sub.3                                                                              S CH N                                       71  O C.sub.2 H.sub.5                                                                         H  CH.sub.3 CH.sub.3                                                                              S CH N                                       72  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               OCH.sub.3                                                                             S N  N                                       73  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               CH.sub.3                                                                              S N  N                                       74  O C.sub.2 H.sub.5                                                                         H  CH.sub.3 CH.sub.3                                                                              S N  N                                       75  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       76  O n-C.sub. 3 H.sub.7                                                                      CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       77  O n-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       78  O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3 CH.sub.3                                                                              O CH N                                       79  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N                                       80  O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3 CH.sub.3                                                                              O N  N                                       81  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       82  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N                                       83  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               Cl     O CH N                                       84  O n-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                             CH.sub.3                                                                              O CH N                                       85  O n-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                             OCF.sub.2 H                                                                           O CH N                                       86  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               Br     O CH N                                       87  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O CH N                                       88  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               SCH.sub.3                                                                             O CH N                                       89  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O N  N                                       90  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OC.sub.3 H.sub.7                                                                      O CH N                                       91  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               Cl     O N  N                                       92  O n-C.sub.3 H.sub.7                                                                       H  Cl       OC.sub.2 H.sub.5                                                                      O CH N                                       93  O n-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                        OC.sub.2 H.sub.5                                                                      O CH N                                       94  O n-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                         OCH.sub.3                                                                             O CH N                                       95  O n-C.sub.3 H.sub.7                                                                       H  CF.sub.3 OCH.sub.3                                                                             O CH N                                       96  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                      CH.sub.3                                                                              O CH N                                       97  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O CH N                                       98  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.2 CF.sub.3                                                                    O CH N                                       99  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O N  N                                       100 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               NHCH.sub.3                                                                            O N  N                                       101 O n-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                        NHCH.sub.3                                                                            O N  N                                       102 O n-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                         OC.sub. 2 H.sub.5                                                                     O N  N                                       103 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       104 O n-C.sub.3 H.sub.7                                                                       H  Cl       CH.sub.3                                                                              O N  N                                       105 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3 CH.sub.3                                                                              O N  N                                       106 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             S CH N                                       107 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              S CH N                                       108 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3 CH.sub.3                                                                              S CH N                                       109 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             S N  N                                       110 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              S N  N                                       111 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3 CH.sub.3                                                                              S N  N                                       112 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N 190-1                                 113 O i-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       114 O i-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       115 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3 CH.sub.3                                                                              O CH N                                       116 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N                                       117 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3 CH.sub.3                                                                              O N  N                                       118 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       119 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N                                       120 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               Cl     O CH N                                       121 O i-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                             CH.sub.3                                                                              O CH N                                       122 O i-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                             OCF.sub.2 H                                                                           O CH N                                       123 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               Br     O CH N                                       124 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O CH N                                       125 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               SCH.sub.3                                                                             O CH N                                       126 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O N  N                                       127 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OC.sub.3 H.sub.7                                                                      O CH N                                       128 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               Cl     O N  N                                       129 O i-C.sub.3 H.sub.7                                                                       H  Cl       OC.sub.2 H.sub.5                                                                      O CH N                                       130 O i-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                        OC.sub.2 H.sub.5                                                                      O CH N                                       131 O i-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                         OCH.sub.3                                                                             O CH N                                       132 O i-C.sub.3 H.sub.7                                                                       H  CF.sub.3 OCH.sub.3                                                                             O CH N                                       133 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                      CH.sub.3                                                                              O CH N                                       134 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O CH N                                       135 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.2 CF.sub.3                                                                    O CH N                                       136 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O N  N                                       137 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               NHCH.sub.3                                                                            O N  N                                       138 O i-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                        NHCH.sub.3                                                                            O N  N                                       139 O i-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                         OC.sub.2 H.sub.5                                                                      O N  N                                       140 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       141 O i-C.sub.3 H.sub.7                                                                       H  Cl       CH.sub.3                                                                              O N  N                                       142 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3 CH.sub.3                                                                              O N  N                                       143 O i-C.sub. 3 H.sub.7                                                                      H  OCH.sub.3                                                                               OCH.sub.3                                                                             S CH N                                       144 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              S CH N                                       145 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3 CH.sub.3                                                                              S CH N                                       146 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             S N  N                                       147 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              S N  N                                       148 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3 CH.sub.3                                                                              S N  N                                       149 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       150 O CH.sub.2 CHCH.sub.2                                                                     CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       151 O CH.sub.2 CHCH.sub.2                                                                     CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       152 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3 CH.sub.3                                                                              O CH N                                       153 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N                                       154 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3 CH.sub.3                                                                              O N  N                                       155 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       156 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N                                       157 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               Cl     O CH N                                       158 O CH.sub.2 CHCH.sub.2                                                                     H  OCF.sub.2 H                                                                             CH.sub.3                                                                              O CH N                                       159 O CH.sub.2 CHCH.sub.2                                                                     H  OCF.sub.2 H                                                                             OCF.sub.2 H                                                                           O CH N                                       160 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               Br     O CH N                                       161 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O CH N                                       162 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               SCH.sub.3                                                                             O CH N                                       163 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O N  N                                       164 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               OC.sub.3 H.sub.7                                                                      O CH N                                       165 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               Cl     O N  N                                       166 O CH.sub.2 CHCH.sub.2                                                                     H  Cl       OC.sub.2 H.sub.5                                                                      O CH N                                       167 O CH.sub.2 CHCH.sub.2                                                                     H  OC.sub.2 H.sub.5                                                                        OC.sub.2 H.sub.5                                                                      O CH N                                       168 O CH.sub.2 CHCH.sub.2                                                                     H  C.sub.2 H.sub.5                                                                         OCH.sub.3                                                                             O CH N                                       169 O CH.sub.2 CHCH.sub.2                                                                     H  CF.sub.3 OCH.sub.3                                                                             O CH N                                       170 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                      CH.sub.3                                                                              O CH N                                       171 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O CH N                                       172 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.2 CF.sub.3                                                                    O CH N                                       173 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O N  N                                       174 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               NHCH.sub.3                                                                            O N  N                                       175 O CH.sub.2 CHCH.sub.2                                                                     H  OC.sub.2 H.sub.5                                                                        NHCH.sub.3                                                                            O N  N                                       176 O CH.sub.2 CHCH.sub.2                                                                     H  C.sub.2 H.sub.5                                                                         OC.sub.2 H.sub.5                                                                      O N  N                                       177 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       178 O CH.sub.2 CHCH.sub.2                                                                     H  Cl       CH.sub.3                                                                              O N  N                                       179 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3 CH.sub.3                                                                              O N  N                                       180 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               OCH.sub.3                                                                             S CH N                                       181 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub. 3                                                                              CH.sub.3                                                                              S CH N                                       182 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3 CH.sub.3                                                                              S CH N                                       183 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               OCH.sub.3                                                                             S N  N                                       184 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                               CH.sub.3                                                                              S N  N                                       185 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3 CH.sub.3                                                                              S N  N                                       186 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       187 O CH.sub.2 CCH                                                                            CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       188 O CH.sub.2 CCH                                                                            CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       189 O CH.sub.2 CCH                                                                            H  CH.sub.3 CH.sub.3                                                                              O CH N                                       190 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N                                       191 O CH.sub.2 CCH                                                                            H  CH.sub. 3                                                                               CH.sub.3                                                                              O N  N                                       192 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       193 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N                                       194 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               Cl     O CH N                                       195 O CH.sub.2 CCH                                                                            H  OCF.sub.2 H                                                                             CH.sub.3                                                                              O CH N                                       196 O CH.sub.2 CCH                                                                            H  OCF.sub.2 H                                                                             OCF.sub.2 H                                                                           O CH N                                       197 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               Br     O CH N                                       198 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O CH N                                       199 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               SCH.sub.3                                                                             O CH N                                       200 O CH.sub.2 C CH                                                                           H  OCH.sub.3                                                                               OC.sub.2 H.sub.5                                                                      O N  N                                       201 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               OC.sub.3 H.sub.7                                                                      O CH N                                       202 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               Cl     O N  N                                       203 O CH.sub.2 CCH                                                                            H  Cl       OC.sub.2 H.sub.5                                                                      O CH N                                       204 O CH.sub.2 CCH                                                                            H  OC.sub.2 H.sub.5                                                                        OC.sub.2 H.sub.5                                                                      O CH N                                       205 O CH.sub.2 CCH                                                                            H  C.sub.2 H.sub.5                                                                         OCH.sub.3                                                                             O CH N                                       206 O CH.sub.2 CCH                                                                            H  CF.sub.3 OCH.sub.3                                                                             O CH N                                       207 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                      CH.sub.3                                                                              O CH N                                       208 O CH.sub.2 C CH                                                                           H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O CH N                                       209 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.2 CF.sub.3                                                                    O CH N                                       210 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O N  N                                       211 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               NHCH.sub.3                                                                            O N  N                                       212 O CH.sub.2 CCH                                                                            H  OC.sub.2 H.sub.5                                                                        NHCH.sub.3                                                                            O N  N                                       213 O CH.sub.2 CCH                                                                            H  C.sub.2 H.sub.5                                                                         OC.sub.2 H.sub.5                                                                      O N  N                                       214 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       215 O CH.sub.2 CCH                                                                            H  Cl       CH.sub.3                                                                              O N  N                                       216 O CH.sub.2 C CH                                                                           H  CH.sub.3 CH.sub.3                                                                              O N  N                                       217 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               OCH.sub.3                                                                             S CH N                                       218 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               CH.sub.3                                                                              S CH N                                       219 O CH.sub.2 CCH                                                                            H  CH.sub.3 CH.sub.3                                                                              S CH N                                       220 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               OCH.sub.3                                                                             S N  N                                       221 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                               CH.sub.3                                                                              S N  N                                       222 O CH.sub.2 CCH                                                                            H  CH.sub.3 CH.sub.3                                                                              S N  N                                       223 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       224 O n-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       225 O n-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       226 O n-C.sub.4 H.sub.9                                                                       H  CH.sub.3 CH.sub.3                                                                              O CH N                                       227 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N                                       228 O n-C.sub.4 H.sub.9                                                                       H  CH.sub.3 CH.sub.3                                                                              O N  N                                       229 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       230 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N                                       231 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       232 O i-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       233 O i-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       234 O i-C.sub.4 H.sub.9                                                                       H  CH.sub.3 CH.sub.3                                                                              O CH N                                       235 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N                                       236 O i-C.sub.4 H.sub.9                                                                       H  CH.sub.3 CH.sub.3                                                                              O N  N                                       237 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       238 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N                                       239 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       240 O sec.-C.sub.4 H.sub.9                                                                    CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub. 3                                                                            O CH N                                       241 O sec.-C.sub.4 H.sub.9                                                                    CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       242 O sec.-C.sub.4 H.sub.9                                                                    H  CH.sub.3 CH.sub.3                                                                              O CH N                                       243 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N                                       244 O sec.-C.sub.4 H.sub.9                                                                    H  CH.sub.3 CH.sub.3                                                                              O N  N                                       245 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       246 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N                                       247 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       248 O t-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       249 O t-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       250 O t-C.sub.4 H.sub.9                                                                       H  CH.sub.3 CH.sub.3                                                                              O CH N                                       251 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N                                       252 O t-C.sub.4 H.sub.9                                                                       H  CH.sub.3 CH.sub.3                                                                              O N  N                                       253 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       254 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N                                       255 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       256 O CH.sub.2 CH.sub.2 Cl                                                                    CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       257 O CH.sub.2 CH.sub.2 Cl                                                                    CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       258 O CH.sub.2 CH.sub.2 Cl                                                                    H  CH.sub.3 CH.sub.3                                                                              O CH N                                       259 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N                                       260 O CH.sub.2 CH.sub.2 Cl                                                                    H  CH.sub.3 CH.sub.3                                                                              O N  N                                       261 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       262 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N                                       263 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       264 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       265 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       266 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  CH.sub.3 CH.sub.3                                                                              O CH N                                       267 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N                                       268 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  CH.sub.3 CH.sub.3                                                                              O N  N                                       269 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       270 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N                                       271 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       272 O c-C.sub.6 H.sub.11                                                                      CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N                                       273 O c-C.sub.6 H.sub.11                                                                      CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       274 O c-C.sub.6 H.sub.11                                                                      H  CH.sub.3 CH.sub.3                                                                              O CH N                                       275 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N                                       276 O c-C.sub.6 H.sub.11                                                                      H  CH.sub.3 CH.sub.3                                                                              O N  N                                       277 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N                                       278 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N                                       279 O CH.sub.3 H  OCH.sub.3                                                                               SCH.sub.3                                                                             O N  N 185-7                                 280 O CH.sub.3 H  SCH.sub.3                                                                               CH.sub.3                                                                              O N  N 188                                   281 O CH.sub.3 H  OCH.sub.3                                                                               C.sub.2 H.sub.5                                                                       O N  N 177-8                                 282 O CH.sub.3 H  c-C.sub.3 H.sub.5                                                                       OCH.sub.3                                                                             O N  N 180-1                                 283 O CH.sub.3 H  CH.sub.2 SCH.sub.3                                                                      OCH.sub.3                                                                             O N  N 108                                   284 O CH.sub.3 H  CH.sub.2 CH(OCH.sub.3).sub.2                                                            OCH.sub.3                                                                             O N  N 137-8                                 285 O CH.sub.3 H                                                                                  ##STR20##                                                                              OCH.sub.3                                                                             O N  N 157-8                                 286 O CH.sub.3 H  i-C.sub.3 H.sub.7                                                                       OCH.sub.3                                                                             O N  N 164-5                                 287 O CH.sub.3 H  n-C.sub.3 H.sub.7                                                                       OCH.sub.3                                                                             O N  N 154-5                                 288 O CH.sub.3 H  CH.sub.2 Cl                                                                             OCH.sub.3                                                                             O N  N 178-9                                 289 O CH.sub.3 H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N 150-5                                 290 O CH.sub.3 H  OCH.sub.3                                                                               CH(OCH.sub.3).sub.2                                                                   O N  N 108                                   291 O CH.sub.3 H  OCH.sub.3                                                                               SCH.sub.3                                                                             O N  N 153-5                                 292 O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N 158-60                                293 O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N Na-salt                                                                        230-3                                 294 O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N Na-salt                                                                        251-3                                 295 O CH.sub.3 H  CH.sub.3 CH.sub.3                                                                              O CH N Na-salt                                                                        108                                   296 O CH.sub.3 H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N Na-salt                                                                        135                                   297 O CH.sub.3 H  CH.sub.3 CH.sub.3                                                                              O N  N Na-salt                                                                        165                                   298 O CH.sub.3 H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N Na-salt                                                                        155                                   299 O CH.sub.3 H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N Li-salt                                                                        153                                   300 O CH.sub.3 H  OCH.sub.3                                                                               CH.sub.3                                                                              O N  N K-salt                                                                         140                                   301 O CH.sub.3 H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N Na-salt                                                                        155                                   302 O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N Na-salt                                                                        150                                   303 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N Na-salt                                                                        160                                   304 O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                             O N  N Na-salt                                                                        110                                   305 O CH.sub.3 H  OC.sub.2 H.sub.5                                                                        NHCH.sub.3                                                                            O N  N Na-salt                                                                        115                                   306 O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O CH N Na-salt                                                                        115                                   307 O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               CH.sub.3                                                                              O CH N Na-salt                                                                        145                                   308 O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               Cl     O CH N Na-salt                                                                        150                                   309 O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                               CH.sub.3                                                                              O N  N Na-salt                                                                        113                                   310 O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N Na-salt                                                                        140                                   311 O CH.sub.3 H  OCH.sub.3                                                                               C.sub.2 H.sub.5                                                                       O N  N Na-salt                                                                        132                                   312 O CH.sub.3 H  CH.sub.2 CH(OCH.sub.3).sub.2                                                            OCH.sub.3                                                                             O N  N Na-salt                                                                        155                                   313 O CH.sub.3 H  CH.sub.2 SCH.sub.3                                                                      OCH.sub.3                                                                             O N  N Na-salt                                                                        145                                   314 O CH.sub.3 H  i-C.sub.3 H.sub.7                                                                       OCH.sub.3                                                                             O N  N Na-salt                                                                        155                                   315 O CH.sub.3 H  n-C.sub.3 H.sub.7                                                                       OCH.sub.3                                                                             O N  N Na-salt                                                                        157                                   316 O CH.sub.3 H  CH.sub.2 Cl                                                                             OCH.sub.3                                                                             O N  N Na-salt                                                                        185                                   317 O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N Na-salt                                                                        227-30                                318 O CH.sub.3 H  OCH.sub.3                                                                               CH(OCH.sub.3).sub.2                                                                   O N  N Na-salt                                                                        135                                   319 O CH.sub.3 H  SCH.sub.3                                                                               CH.sub.3                                                                              O N  N Na-salt                                                                        165                                   320 O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                               OCH.sub.3                                                                             O N  N Na-salt                                                                        115                                   __________________________________________________________________________

                                      TABLE 4                                      __________________________________________________________________________      ##STR21##                                                                     Ex.                                  M.p.                                      No. Q R        R.sup.1                                                                           R.sup.2                                                                              R.sup.3                                                                              W Y  Z [°C.]                              __________________________________________________________________________     1   O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N 190-2                                     2   O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           3   O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           4   O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           5   O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           6   O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           7   O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           8   O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           9   O CH.sub.3 H  OCH.sub.3                                                                            Cl    O CH N                                           10  O CH.sub.3 H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           11  O CH.sub.3 H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           12  O CH.sub.3 H  OCH.sub.3                                                                            Br    O CH N                                           13  O CH.sub.3 H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           14  O CH.sub.3 H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           15  O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.2 H.sub.5                                                                    O N  N                                           16  O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3 H.sub.7                                                                    O CH N                                           17  O CH.sub.3 H  OCH.sub.3                                                                            Cl    O N  N                                           18  O CH.sub.3 H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           19  O CH.sub.3 H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           20  O CH.sub.3 H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           21  O CH.sub.3 H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           22  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           23  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           24  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           25  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           26  O CH.sub.3 H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           27  O CH.sub.3 H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           28  O CH.sub.3 H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           29  O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           30  O CH.sub.3 H  Cl    CH.sub.3                                                                             O N  N                                           31  O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           32  O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           33  O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           34  O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           35  O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           36  O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           37  O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           38  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           39  O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           40  O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           41  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           42  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           43  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           44  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           45  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           46  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            Cl    O CH N                                           47  O C.sub.2 H.sub.5                                                                         H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           48  O C.sub.2 H.sub.5                                                                         H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           49  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            Br    O CH N                                           50  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           51  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            SCH.sub. 3                                                                           O CH N                                           52  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           53  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           54  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            Cl    O N  N                                           55  O C.sub.2 H.sub.5                                                                         H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           56  O C.sub.2 H.sub.5                                                                         H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           57  O C.sub.2 H.sub.5                                                                         H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           58  O C.sub.2 H.sub.5                                                                         H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           59  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           60  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           61  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           62  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           63  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           64  O C.sub.2 H.sub.5                                                                         H  OC.sub. 2 H.sub.5                                                                    NHCH.sub.3                                                                           O N  N                                           65  O C.sub.2 H.sub.5                                                                         H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           66  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           67  O C.sub.2 H.sub.5                                                                         H  Cl    CH.sub.3                                                                             O N  N                                           68  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           69  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           70  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           71  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           72  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           73  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           74  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           75  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           76  O n-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           77  O n-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           78  O n-C.sub.3 H.sub. 7                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           79  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           80  O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           81  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           82  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           83  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O CH N                                           84  O n-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           85  O n-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           86  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Br    O CH N                                           87  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           88  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           89  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           90  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           91  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O N  N                                           92  O n-C.sub. 3 H.sub.7                                                                      H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           93  O n-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           94  O n-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           95  O n-C.sub.3 H.sub.7                                                                       H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           96  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           97  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           98  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           99  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           100 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           101 O n-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           102 O n-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           103 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           104 O n-C.sub.3 H.sub.7                                                                       H  Cl    CH.sub.3                                                                             O N  N                                           105 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           106 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           107 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           108 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           109 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           110 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           111 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           112 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           113 O i-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           114 O i-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           115 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           116 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           117 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           118 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           119 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           120 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O CH N                                           121 O i-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           122 O i-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           123 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Br    O CH N                                           124 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           125 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           126 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           127 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           128 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O N  N                                           129 O i-C.sub.3 H.sub.7                                                                       H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           130 O i-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           131 O i-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           132 O i-C.sub.3 H.sub.7                                                                       H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           133 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           134 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           135 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           136 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           137 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           138 O i-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           139 O i-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           140 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           141 O i-C.sub.3 H.sub.7                                                                       H  Cl    CH.sub.3                                                                             O N  N                                           142 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           143 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           144 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           145 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           146 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           147 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           148 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           149 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           150 O CH.sub.2 CHCH.sub.2                                                                     CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           151 O CH.sub.2 CHCH.sub.2                                                                     CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           152 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           153 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           154 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           155 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           156 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           157 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            Cl    O CH N                                           158 O CH.sub.2 CHCH.sub.2                                                                     H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           159 O CH.sub.2 CHCH.sub.2                                                                     H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           160 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            Br    O CH N                                           161 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           162 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           163 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           164 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           165 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            Cl    O N  N                                           166 O CH.sub.2 CHCH.sub.2                                                                     H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           167 O CH.sub.2 CHCH.sub.2                                                                     H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           168 O CH.sub.2 CHCH.sub.2                                                                     H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           169 O CH.sub.2 CHCH.sub.2                                                                     H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           170 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           171 O CH.sub.2 CHCH.sub. 2                                                                    H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           172 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           173 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           174 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           175 O CH.sub.2 CHCH.sub.2                                                                     H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           176 O CH.sub.2 CHCH.sub.2                                                                     H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           177 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           178 O CH.sub.2 CHCH.sub.2                                                                     H  Cl    CH.sub.3                                                                             O N  N                                           179 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           180 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           181 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           182 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           183 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           184 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           185 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           186 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           187 O CH.sub.2 CCH                                                                            CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           188 O CH.sub.2 CCH                                                                            CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           189 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           190 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           191 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           192 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           193 O CH.sub.2 C CH                                                                           H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           194 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            Cl    O CH N                                           195 O CH.sub.2 CCH                                                                            H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           196 O CH.sub.2 CCH                                                                            H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           197 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            Br    O CH N                                           198 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           199 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           200 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           201 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           202 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            Cl    O N  N                                           203 O CH.sub.2 CCH                                                                            H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           204 O CH.sub.2 CCH                                                                            H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           205 O CH.sub.2 CCH                                                                            H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           206 O CH.sub.2 CCH                                                                            H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           207 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           208 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           209 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           210 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           211 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           212 O CH.sub.2 CCH                                                                            H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           213 O CH.sub.2 CCH                                                                            H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           214 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           215 O CH.sub.2 CCH                                                                            H  Cl    CH.sub.3                                                                             O N  N                                           216 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           217 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           218 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           219 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           220 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           221 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           222 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           223 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           224 O n-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           225 O n-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           226 O n-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           227 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           228 O n-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           229 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           230 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           231 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           232 O i-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           233 O i-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           234 O i-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           235 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           236 O i-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           237 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           238 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           239 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           240 O sec.-C.sub.4 H.sub.9                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           241 O sec.-C.sub.4 H.sub.9                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           242 O sec.-C.sub.4 H.sub.9                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           243 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           244 O sec.-C.sub.4 H.sub.9                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           245 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           246 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           247 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           248 O t-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           249 O t-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           250 O t-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           251 O t -C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           252 O t-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           253 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           254 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           255 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           256 O CH.sub.2 CH.sub.2 Cl                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           257 O CH.sub.2 CH.sub.2 Cl                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           258 O CH.sub.2 CH.sub.2 Cl                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           259 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           260 O CH.sub.2 CH.sub.2 Cl                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           261 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           262 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           263 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           264 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           265 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           266 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           267 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           268 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           269 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub. 3                                                                           CH.sub.3                                                                             O N  N                                           270 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           271 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           272 O c-C.sub.6 H.sub.11                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           273 O c-C.sub.6 H.sub.11                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           274 O c-C.sub.6 H.sub.11                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           275 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           276 O c-C.sub.6 H.sub.11                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           277 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           278 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           __________________________________________________________________________

                                      TABLE 5                                      __________________________________________________________________________      ##STR22##                                                                     Ex.                                  M.p.                                      No. Q R        R.sup.1                                                                           R.sup.2                                                                              R.sup.3                                                                              W Y  Z [°C.]                              __________________________________________________________________________     1   O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N 199-202                                   2   O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           3   O CH.sub.3 CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           4   O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N 212-5                                     5   O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N 193-4                                     6   O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N 196-7                                     7   O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N 192                                       8   O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           9   O CH.sub.3 H  OCH.sub.3                                                                            Cl    O CH N                                           10  O CH.sub.3 H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           11  O CH.sub.3 H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           12  O CH.sub.3 H  OCH.sub.3                                                                            Br    O CH N                                           13  O CH.sub.3 H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           14  O CH.sub.3 H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           15  O CH.sub.3 H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           16  O CH.sub.3 H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           17  O CH.sub.3 H  OCH.sub.3                                                                            Cl    O N  N                                           18  O CH.sub.3 H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           19  O CH.sub.3 H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           20  O CH.sub.3 H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           21  O CH.sub.3 H  CF.sub.3                                                                             OCH.sub. 3                                                                           O CH N                                           22  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           23  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           24  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           25  O CH.sub.3 H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           26  O CH.sub.3 H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           27  O CH.sub.3 H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           28  O CH.sub.3 H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           29  O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           30  O CH.sub.3 H  Cl    CH.sub.3                                                                             O N  N                                           31  O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           32  O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           33  O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           34  O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           35  O CH.sub.3 H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           36  O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           37  O CH.sub.3 H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           38  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N 182                                       39  O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           40  O C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           41  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           42  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           43  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           44  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N 177-179                                   45  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           46  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            Cl    O CH N                                           47  O C.sub.2 H.sub.5                                                                         H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           48  O C.sub.2 H.sub.5                                                                         H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           49  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            Br    O CH N                                           50  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           51  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           52  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           53  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           54  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            Cl    O N  N                                           55  O C.sub.2 H.sub.5                                                                         H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           56  O C.sub.2 H.sub.5                                                                         H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           57  O C.sub.2 H.sub.5                                                                         H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           58  O C.sub.2 H.sub.5                                                                         H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           59  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           60  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           61  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           62  O C.sub.2 H.sub.5                                                                         H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           63  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           64  O C.sub.2 H.sub.5                                                                         H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           65  O C.sub.2 H.sub.5                                                                         H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           66  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           67  O C.sub.2 H.sub.5                                                                         H  Cl    CH.sub.3                                                                             O N  N                                           68  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           69  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           70  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           71  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           72  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           73  O C.sub.2 H.sub.5                                                                         H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           74  O C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           75  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N 186-188                                   76  O n-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           77  O n-C.sub.3 H.sub.7                                                                       CH.sub. 3                                                                         OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           78  O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           79  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           80  O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           81  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N 107-108                                   82  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           83  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O CH N                                           84  O n-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           85  O n-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           86  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Br    O CH N                                           87  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           88  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           89  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           90  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           91  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O N  N                                           92  O n-C.sub.3 H.sub.7                                                                       H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           93  O n-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           94  O n-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           95  O n-C.sub.3 H.sub.7                                                                       H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           96  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           97  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           98  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           99  O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           100 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           101 O n-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           102 O n-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           103 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           104 O n-C.sub.3 H.sub.7                                                                       H  Cl    CH.sub.3                                                                             O N  N                                           105 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           106 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           107 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           108 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           109 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           110 O n-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           111 O n-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           112 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N 185                                       113 O i-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           114 O i-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           115 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           116 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           117 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           118 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N 150                                       119 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           120 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O CH N                                           121 O i-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           122 O i-C.sub.3 H.sub.7                                                                       H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           123 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Br    O CH N                                           124 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           125 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           126 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           127 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           128 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            Cl    O N  N                                           129 O i-C.sub.3 H.sub.7                                                                       H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           130 O i-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           131 O i-C.sub.3 H.sub. 7                                                                      H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           132 O i-C.sub.3 H.sub.7                                                                       H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           133 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           134 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           135 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           136 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           137 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           138 O i-C.sub.3 H.sub.7                                                                       H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           139 O i-C.sub.3 H.sub.7                                                                       H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           140 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           141 O i-C.sub.3 H.sub.7                                                                       H  Cl    CH.sub.3                                                                             O N  N                                           142 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           143 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           144 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           145 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           146 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           147 O i-C.sub.3 H.sub.7                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           148 O i-C.sub.3 H.sub.7                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           149 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           150 O CH.sub.2 CHCH.sub.2                                                                     CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           151 O CH.sub.2 CHCH.sub.2                                                                     CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           152 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           153 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           154 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           155 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           156 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           157 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            Cl    O CH N                                           158 O CH.sub.2 CHCH.sub.2                                                                     H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           159 O CH.sub.2 CHCH.sub.2                                                                     H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           160 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            Br    O CH N                                           161 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           162 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           163 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           164 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           165 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            Cl    O N  N                                           166 O CH.sub.2 CHCH.sub.2                                                                     H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           167 O CH.sub.2 CHCH.sub.2                                                                     H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           168 O CH.sub.2 CHCH.sub.2                                                                     H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           169 O CH.sub.2 CHCH.sub.2                                                                     H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           170 O CH.sub.2 CHCH.sub. 2                                                                    H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           171 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           172 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           173 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           174 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           175 O CH.sub.2 CHCH.sub.2                                                                     H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           176 O CH.sub.2 CHCH.sub.2                                                                     H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           177 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           178 O CH.sub.2 CHCH.sub.2                                                                     H  Cl    CH.sub.3                                                                             O N  N                                           179 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           180 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           181 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           182 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub. 3                                                                            S CH N                                           183 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           184 O CH.sub.2 CHCH.sub.2                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           185 O CH.sub.2 CHCH.sub.2                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           186 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           187 O CH.sub.2 CCH                                                                            CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           188 O CH.sub.2 CCH                                                                            CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           189 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           190 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           191 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           192 O CH.sub.2 C CH                                                                           H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           193 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           194 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            Cl    O CH N                                           195 O CH.sub.2 CCH                                                                            H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           196 O CH.sub.2 CCH                                                                            H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           197 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            Br    O CH N                                           198 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           199 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           200 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           201 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           202 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            Cl    O N  N                                           203 O CH.sub.2 CCH                                                                            H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           204 O CH.sub.2 CCH                                                                            H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           205 O CH.sub.2 CCH                                                                            H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           206 O CH.sub.2 CCH                                                                            H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           207 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           208 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           209 O CH.sub. 2 CCH                                                                           H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           210 O CH.sub.2 CCH                                                                            H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           211 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           212 O CH.sub.2 CCH                                                                            H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           213 O CH.sub.2 CCH                                                                            H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           214 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           215 O CH.sub.2 CCH                                                                            H  Cl    CH.sub.3                                                                             O N  N                                           216 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           217 O CH.sub.2 C CH                                                                           H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           218 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           219 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           220 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           221 O CH.sub.2 CCH                                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           222 O CH.sub.2 CCH                                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           223 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           224 O n-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           225 O n-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           226 O n-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           227 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           228 O n-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           229 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           230 O n-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           231 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           232 O i-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           233 O i-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           234 O i-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           235 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           236 O i-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           237 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           238 O i-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           239 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           240 O sec.-C.sub.4 H.sub.9                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           241 O sec.-C.sub.4 H.sub.9                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           242 O sec.-C.sub.4 H.sub.9                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           243 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           244 O sec.-C.sub.4 H.sub.9                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           245 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           246 O sec.-C.sub.4 H.sub.9                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           247 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           248 O t-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           249 O t-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           250 O t-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           251 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           252 O t-C.sub.4 H.sub.9                                                                       H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           253 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           254 O t-C.sub.4 H.sub.9                                                                       H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           255 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           256 O CH.sub.2 CH.sub.2 Cl                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           257 O CH.sub.2 CH.sub.2 Cl                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           258 O CH.sub.2 CH.sub.2 Cl                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           259 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           260 O CH.sub.2 CH.sub.2 Cl                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           261 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           262 O CH.sub.2 CH.sub.2 Cl                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           263 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           264 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           265 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           266 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           267 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           268 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  CH.sub. 3                                                                            CH.sub.3                                                                             O N  N                                           269 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           270 O CH.sub.2 CH.sub.2 OCH.sub.3                                                             H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           271 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           272 O c-C.sub.6 H.sub.11                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           273 O c-C.sub.6 H.sub.11                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           274 O c-C.sub.6 H.sub.11                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           275 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           276 O c-C.sub.6 H.sub.11                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           277 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           278 O c-C.sub.6 H.sub.11                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           279 O CH.sub.3 H  CH.sub.3                                                                             Cl    O CH N 214-6 decomp.                             280 O CH.sub.3 H  CH.sub.3                                                                             H     O CH N 201-3 decomp.                             281 O CH.sub.3 H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N Na-salt                                                                        200                                       __________________________________________________________________________

                                      TABLE 6                                      __________________________________________________________________________      ##STR23##                                                                     Ex. No.                                                                             Q R       R.sup.1                                                                           R.sup.2                                                                              R.sup.3                                                                              W Y  Z M.p. [°C.]                         __________________________________________________________________________      1   O CH.sub.3                                                                               H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N 173-177                                    2   O CH.sub.3                                                                               CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                            3   O CH.sub.3                                                                               CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                            4   O CH.sub.3                                                                               H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                            5   O CH.sub.3                                                                               H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                            6   O CH.sub.3                                                                               H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                            7   O CH.sub.3                                                                               H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N 187-188                                    8   O CH.sub.3                                                                               H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                            9   O CH.sub.3                                                                               H  OCH.sub.3                                                                            Cl    O CH N                                            10  O CH.sub.3                                                                               H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                            11  O CH.sub.3                                                                               H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                            12  O CH.sub.3                                                                               H  OCH.sub.3                                                                            Br    O CH N                                            13  O CH.sub.3                                                                               H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                            14  O CH.sub.3                                                                               H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                            15  O CH.sub.3                                                                               H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                            16  O CH.sub.3                                                                               H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                            17  O CH.sub.3                                                                               H  OCH.sub.3                                                                            Cl    O N  N                                            18  O CH.sub.3                                                                               H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                            19  O CH.sub.3                                                                               H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                            20  O CH.sub.3                                                                               H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                            21  O CH.sub.3                                                                               H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                            22  O CH.sub.3                                                                               H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                            23  O CH.sub.3                                                                               H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                            24  O CH.sub.3                                                                               H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                            25  O CH.sub.3                                                                               H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                            26  O CH.sub.3                                                                               H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                            27  O CH.sub.3                                                                               H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                            28  O CH.sub.3                                                                               H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                            29  O CH.sub.3                                                                               H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                            30  O CH.sub.3                                                                               H  Cl    CH.sub.3                                                                             O N  N                                            31  O CH.sub.3                                                                               H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                            32  O CH.sub.3                                                                               H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                            33  O CH.sub.3                                                                               H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                            34  O CH.sub.3                                                                               H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                            35  O CH.sub.3                                                                               H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                            36  O CH.sub.3                                                                               H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                            37  O CH.sub.3                                                                               H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                            38  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                            39  O C.sub.2 H.sub.5                                                                        CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                            40  O C.sub.2 H.sub.5                                                                        CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                            41  O C.sub.2 H.sub.5                                                                        H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                            42  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                            43  O C.sub.2 H.sub.5                                                                        H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                            44  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                            45  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                            46  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            Cl    O CH N                                            47  O C.sub.2 H.sub.5                                                                        H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                            48  O C.sub.2 H.sub.5                                                                        H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                            49  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            Br    O CH N                                            50  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                            51  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                            52  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                            53  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                            54  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            Cl    O N  N                                            55  O C.sub.2 H.sub.5                                                                        H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                            56  O C.sub.2 H.sub.5                                                                        H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                            57  O C.sub.2 H.sub.5                                                                        H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                            58  O C.sub.2 H.sub.5                                                                        H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                            59  O C.sub.2 H.sub.5                                                                        H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                            60  O C.sub.2 H.sub.5                                                                        H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                            61  O C.sub.2 H.sub.5                                                                        H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                            62  O C.sub.2 H.sub.5                                                                        H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                            63  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                            64  O C.sub.2 H.sub.5                                                                        H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                            65  O C.sub.2 H.sub.5                                                                        H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                            66  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                            67  O C.sub.2 H.sub.5                                                                        H  Cl    CH.sub.3                                                                             O N  N                                            68  O C.sub.2 H.sub.5                                                                        H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                            69  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                            70  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                            71  O C.sub.2 H.sub.5                                                                        H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                            72  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                            73  O C.sub.2 H.sub.5                                                                        H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                            74  O C.sub.2 H.sub.5                                                                        H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                            75  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                            76  O n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                            77  O n-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                            78  O n-C.sub.3 H.sub.7                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                            79  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                            80  O n-C.sub.3 H.sub.7                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                            81  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                            82  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                            83  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            Cl    O CH N                                            84  O n-C.sub.3 H.sub.7                                                                      H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                            85  O n-C.sub.3 H.sub.7                                                                      H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                            86  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            Br    O CH N                                             87 O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                            88  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                            89  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                            90  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                            91  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            Cl    O N  N                                            92  O n-C.sub.3 H.sub.7                                                                      H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                            93  O n-C.sub.3 H.sub.7                                                                      H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                            94  O n-C.sub.3 H.sub.7                                                                      H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                            95  O n-C.sub.3 H.sub.7                                                                      H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                            96  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                            97  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                            98  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                             99 O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           100  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           101  O n-C.sub.3 H.sub.7                                                                      H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           102  O n-C.sub.3 H.sub.7                                                                      H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           103  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           104  O n-C.sub.3 H.sub.7                                                                      H  Cl    CH.sub.3                                                                             O N  N                                           105  O n-C.sub.3 H.sub.7                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           106  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           107  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           108  O n-C.sub.3 H.sub.7                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           109  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           110  O n-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           111  O n-C.sub.3 H.sub.7                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           112  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           113  O i-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           114  O i-C.sub.3 H.sub.7                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           115  O i-C.sub.3 H.sub.7                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           116  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           117  O i-C.sub.3 H.sub.7                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           118  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           119  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           120  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            Cl    O CH N                                           121  O i-C.sub.3 H.sub.7                                                                      H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           122  O i-C.sub.3 H.sub.7                                                                      H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           123  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            Br    O CH N                                           124  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           125  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           126  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OC.sub. 2 H.sub.5                                                                    O N  N                                           127  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           128  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            Cl    O N  N                                           129  O i-C.sub.3 H.sub.7                                                                      H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           130  O i-C.sub.3 H.sub.7                                                                      H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           131  O i-C.sub.3 H.sub.7                                                                      H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           132  O i-C.sub.3 H.sub.7                                                                      H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           133  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           134  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           135  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           136  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           137  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           138  O i-C.sub.3 H.sub.7                                                                      H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           139  O i-C.sub.3 H.sub.7                                                                      H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           140  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           141  O i-C.sub.3 H.sub.7                                                                      H  Cl    CH.sub.3                                                                             O N  N                                           142  O i-C.sub.3 H.sub.7                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           143  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           144  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           145  O i-C.sub.3 H.sub.7                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           146  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           147  O i-C.sub.3 H.sub.7                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           148  O i-C.sub.3 H.sub.7                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           149  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           150  O CH.sub.2 CHCH.sub.2                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           151  O CH.sub.2 CHCH.sub.2                                                                    CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           152  O CH.sub.2 CHCH.sub.2                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           153  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           154  O CH.sub.2 CHCH.sub.2                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           155  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           156  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           157  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            Cl    O CH N                                           158  O CH.sub.2 CHCH.sub.2                                                                    H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           159  O CH.sub.2 CHCH.sub.2                                                                    H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           160  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            Br    O CH N                                           161  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           162  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           163  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           164  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           165  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            Cl    O N  N                                           166  O CH.sub.2 CHCH.sub.2                                                                    H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           167  O CH.sub.2 CHCH.sub.2                                                                    H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           168  O CH.sub.2 CHCH.sub.2                                                                    H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           169  O CH.sub.2 CHCH.sub.2                                                                    H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           170  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                                                             O CH N                                           171  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           172  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           173  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           174  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           175  O CH.sub.2 CHCH.sub.2                                                                    H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           176  O CH.sub.2 CHCH.sub.2                                                                    H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           177  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           178  O CH.sub.2 CHCH.sub.2                                                                    H  Cl    CH.sub.3                                                                             O N  N                                           179  O CH.sub.2 CHCH.sub.2                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           180  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           181  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           182  O CH.sub.2 CHCH.sub.2                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           183  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           184  O CH.sub.2 CHCH.sub.2                                                                    H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           185  O CH.sub.2 CHCH.sub.2                                                                    H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           186  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           187  O CH.sub.2 CCH                                                                           CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           188  O CH.sub.2 CCH                                                                           CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           189  O CH.sub.2 C CH                                                                          H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           190  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           191  O CH.sub.2 CCH                                                                           H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           192  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           193  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           194  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            Cl    O CH N                                           195  O CH.sub.2 CCH                                                                           H  OCF.sub.2 H                                                                          CH.sub.3                                                                             O CH N                                           196  O CH.sub.2 CCH                                                                           H  OCF.sub.2 H                                                                          OCF.sub.2 H                                                                          O CH N                                           197  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            Br    O CH N                                           198  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O CH N                                           199  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            SCH.sub.3                                                                            O CH N                                           200  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                     O N  N                                           201  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            OC.sub.3 H.sub.7                                                                     O CH N                                           202  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            Cl    O N  N                                           203  O CH.sub.2 CCH                                                                           H  Cl    OC.sub.2 H.sub.5                                                                     O CH N                                           204  O CH.sub.2 CCH                                                                           H  OC.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5                                                                     O CH N                                           205  O CH.sub.2 CCH                                                                           H  C.sub.2 H.sub.5                                                                      OCH.sub.3                                                                            O CH N                                           206  O CH.sub. 2 CCH                                                                          H  CF.sub.3                                                                             OCH.sub.3                                                                            O CH N                                           207  O CH.sub.2 CCH                                                                           H  OCH.sub.2 CH.sub.3                                                                   CH.sub.3                                                                             O CH N                                           208  O CH.sub.2 CCH                                                                           H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O CH N                                           209  O CH.sub.2 CCH                                                                           H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.2 CF.sub.3                                                                   O CH N                                           210  O CH.sub.2 CCH                                                                           H  OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                                                            O N  N                                           211  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            NHCH.sub.3                                                                           O N  N                                           212  O CH.sub.2 CCH                                                                           H  OC.sub.2 H.sub.5                                                                     NHCH.sub.3                                                                           O N  N                                           213  O CH.sub.2 CCH                                                                           H  C.sub.2 H.sub.5                                                                      OC.sub.2 H.sub.5                                                                     O N  N                                           214  O CH.sub. 2 CCH                                                                          H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           215  O CH.sub.2 CCH                                                                           H  Cl    CH.sub.3                                                                             O N  N                                           216  O CH.sub.2 CCH                                                                           H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           217  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            OCH.sub.3                                                                            S CH N                                           218  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            CH.sub.3                                                                             S CH N                                           219  O CH.sub.2 CCH                                                                           H  CH.sub.3                                                                             CH.sub.3                                                                             S CH N                                           220  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            OCH.sub.3                                                                            S N  N                                           221  O CH.sub.2 CCH                                                                           H  OCH.sub.3                                                                            CH.sub.3                                                                             S N  N                                           222  O CH.sub.2 CCH                                                                           H  CH.sub.3                                                                             CH.sub.3                                                                             S N  N                                           223  O n-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           224  O n-C.sub.4 H.sub.9                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           225  O n-C.sub.4 H.sub.9                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           226  O n-C.sub.4 H.sub.9                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           227  O n-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           228  O n-C.sub.4 H.sub.9                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           229  O n-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           230  O n-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           231  O i-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           232  O i-C.sub.4 H.sub.9                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           233  O i-C.sub.4 H.sub.9                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           234  O i-C.sub.4 H.sub.9                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           235  O i-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           236  O i-C.sub.4 H.sub.9                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           237  O i-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           238  O i-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           239  O sec. C.sub.4 H.sub.9                                                                   H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           240  O sec. C.sub.4 H.sub.9                                                                   CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           241  O sec. C.sub.4 H.sub.9                                                                   CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           242  O sec. C.sub.4 H.sub.9                                                                   H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           243  O sec. C.sub.4 H.sub.9                                                                   H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           244  O sec. C.sub.4 H.sub.9                                                                   H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           245  O sec. C.sub.4 H.sub.9                                                                   H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           246  O sec. C.sub.4 H.sub.9                                                                   H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           247  O t-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           248  O t-C.sub.4 H.sub.9                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           249  O t-C.sub.4 H.sub.9                                                                      CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           250  O t-C.sub.4 H.sub.9                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           251  O t-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           252  O t-C.sub.4 H.sub.9                                                                      H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           253  O t-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           254  O t-C.sub.4 H.sub.9                                                                      H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           255  O CH.sub.2 CH.sub.2 Cl                                                                   H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           256  O CH.sub.2 CH.sub.2 Cl                                                                   CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           257  O CH.sub.2 CH.sub.2 Cl                                                                   CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           258  O CH.sub.2 CH.sub.2 Cl                                                                   H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           259  O CH.sub.2 CH.sub.2 Cl                                                                   H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           260  O CH.sub.2 CH.sub.2 Cl                                                                   H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           261  O CH.sub.2 CH.sub.2 Cl                                                                   H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           262  O CH.sub.2 CH.sub.2 Cl                                                                   H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           263  O CH.sub. 2 CH.sub.2 OCH.sub.3                                                           H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           264  O CH.sub.2 CH.sub.2 OCH.sub.3                                                            CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           265  O CH.sub.2 CH.sub.2 OCH.sub.3                                                            CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           266  O CH.sub.2 CH.sub.2 OCH.sub.3                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           267  O CH.sub.2 CH.sub.2 OCH.sub.3                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           268  O CH.sub.2 CH.sub.2 OCH.sub.3                                                            H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           269  O CH.sub.2 CH.sub.2 OCH.sub.3                                                            H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           270  O CH.sub.2 CH.sub.2 OCH.sub.3                                                            H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           271  O c-C.sub.6 H.sub.11                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           272  O c-C.sub.6 H.sub.11                                                                     CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3                                                                            O CH N                                           273  O c-C.sub.6 H.sub.11                                                                     CH.sub.3                                                                          OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           274  O c-C.sub.6 H.sub.11                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             O CH N                                           275  O c-C.sub.6 H.sub.11                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             O CH N                                           276  O c-C.sub.6 H.sub.11                                                                     H  CH.sub.3                                                                             CH.sub.3                                                                             O N  N                                           277  O c-C.sub.6 H.sub.11                                                                     H  OCH.sub.3                                                                            CH.sub.3                                                                             O N  N                                           278  O c-C.sub.6 H.sub.11                                                                     H  OCH.sub.3                                                                            OCH.sub.3                                                                            O N  N                                           __________________________________________________________________________

B. Formulation Examples

a) A dust is obtained by mixing 10 parts by weight of a compound of the formula (I) and 90 parts by weight of talc as inert substance and comminuting the mixture in a hammer mill.

b) A wettable powder which is readily dispersible in water is obtained by mixing 25 parts by weight of a compound of the formula (I), 64 parts by weight of kaolin-containing quartz as inert substance, 10 parts by weight of potassium ligninsulfonate and 1 part by weight of sodium oleylmethyltauride as wetting and dispersing agent, and grinding the mixture in a pinned disk mill.

c) A dispersion concentrate which is readily dispersible in water is obtained by mixing 20 parts by weight of a compound of the formula (I) with 6 parts by weight of alkylphenol polyglycol ether ((R)Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 parts by weight of paraffinic mineral oil (boiling range for example approx. 255° up to above 277° C.), and grinding the mixture in a ball mill to a fineness of below 5 microns.

d) An emulsifiable concentrate is obtained from 15 parts by weight of a compound of the formula (I), 75 parts by weight of cyclohexane as solvent and 10 parts by weight of ethoxylated nonylphenol as emulsifier.

e) Water-dispersible granules are obtained by mixing

    ______________________________________                                         75    parts by weight                                                                            of a compound of the formula (I),                            10    parts by weight                                                                            of calcium ligninsulfonate,                                  5     parts by weight                                                                            of sodium lauryl sulfate,                                    3     parts by weight                                                                            of polyvinyl alcohol and                                     7     parts by weight                                                                            of kaolin,                                                   ______________________________________                                    

grinding the mixture on a pinned disk mill, and granulating the powder in a fluidized bed by spraying on water as granulation liquid.

f) Alternatively, water-dispersible granules are obtained by homogenizing and precomminuting

    ______________________________________                                         25    parts by weight                                                                            of a compound of the formula (I),                            5     parts by weight                                                                            of sodium 2,2'-dinaphthylmethane-                                              6,6'-disulfonate,                                            2     parts by weight                                                                            of sodium oleylmethyltauride,                                1     part by weight                                                                             of polyvinyl alcohol,                                        17    parts by weight                                                                            of calcium carbonate and                                     50    parts by weight                                                                            of water                                                     ______________________________________                                    

on a colloid mill, subsequently grinding the mixture on a bead mill, and atomizing and drying the resulting suspension in a spray tower by means of a single-substance nozzle.

g) Extruder granules are obtained by mixing 20 parts by weight of active substance, 3 parts by weight of sodium ligninsulfonate, 1 part by weight of carboxymethylcellulose and 76 parts by weight of kaolin, grinding the mixture and moistening it with water. This mixture is extruded and subsequently dried in a stream of air.

C. Biological Examples

The damage to the weed plants, or the tolerance by the crop plants, was scored using a key in which the effectiveness is expressed by figures from 0 to 5. The figures have the following meaning:

0=no effect or damage

1=0 to 20% effect or damage

2=20 to 40% effect or damage

3=40 to 60% effect or damage

4=60 to 80% effect or damage

5=80 to 100% effect or damage

1. Pre-emergence effect on weeds

Seeds or rhizome pieces of monocotyledon and dicotyledon weed plants were placed in sandy loam soil in plastic pots and covered with soil. The compounds according to the invention which were formulated in the form of wettable powders or emulsion concentrates were then applied to the surface of the soil cover in the form of aqueous suspensions or emulsions at an application rate of 600-800 1 of water/ha (converted), in various dosages. After the treatment, the pots were placed in a greenhouse and kept under good growth conditions for the weeds. After the test plants had emerged, the damage to the plants or the negative effect on the emergence was scored visually after a test period of 3 to 4 weeks by comparison with untreated controls. As shown by the score figures in Table 7, the compounds according to the invention have a good herbicidal pre-emergence action against a broad range of grass weeds and dicotyledon weeds.

                                      TABLE 7                                      __________________________________________________________________________     Pre-emergence effect                                                           Active                                                                               Dosage                                                                   substance                                                                            rate in                                                                               Herbicidal effect                                                 Tab./Ex.                                                                             kg of ai/ha                                                                           STME                                                                               CRSE                                                                               SIAL                                                                               LOMU                                                                               ECCR                                                                               AVSA                                          __________________________________________________________________________     5/1   0.3    5   5   4   3   3   3                                             3/1   0.3    5   5   5   5   5   4                                             __________________________________________________________________________     Abbreviations:                                                                 STME = Stellaria media                                                         CRSE = Chrysanthemum segetum                                                   SIAL = Sinapis alba                                                            LOMU = Lolium multiflorum                                                      ECCR = Echinochloa crus-galli                                                  AVSA = Avena sativa                                                            a.i. = Active ingredient                                                  

Similarly good activities are generally also found in the case of the other compounds of Tables 2 to 7.

2. Post-emergence effect on weeds

Seeds or rhizome pieces of monocotyledon and dicotyledon weeds were placed in sandy loam soil in plastic pots, covered with soil and grown in a greenhouse under good growth conditions. Three weeks after sowing, the test plants were treated in the three-leaf stage.

The compounds according to the invention which were formulated as wettable powders or as emulsion concentrates were sprayed in various dosages on the green parts of the plants at an application rate of 600 to 800 l of water/ha (converted) and, after the test plants had remained in the greenhouse for about 3-4 weeks under ideal growth conditions, the effect of the preparations was scored visually by comparison with untreated controls.

The agents according to the invention also have a good herbicidal post-emergence action against a broad range of economically important grass weeds and dicotyledon weeds (Table 8).

                                      TABLE 8                                      __________________________________________________________________________     Post-emergence effect                                                          Active                                                                               Dosage                                                                   substance                                                                            rate in                                                                               Herbicidal effect                                                 Tab./Ex.                                                                             kg of ai/ha                                                                           STME                                                                               CRSE                                                                               SIAL                                                                               LOMU                                                                               ECCR                                                                               AVSA                                          __________________________________________________________________________     3/1   0.3    5   5   5   5   5   2                                             __________________________________________________________________________     Abbreviations:                                                                 STME = Stellaria media                                                         CRSE = Chrysanthemum segetum                                                   SIAL = Sinapis alba                                                            LOMU = Lolium multiflorum                                                      ECCR = Echinochloa crus-galli                                                  AVSA = Avena sativa                                                            a.i. = Active ingredient                                                  

Similarly good activities are generally also found in the case of the other compounds of Tables 2 to. 7. Compared with compounds of EP-A-7687 or US-A-4,556,898, the compounds of the formula I according to the invention generally exhibit better activities against problem weeds such as Galium aparine or Echinochloa crus-galli.

3. Tolerance by crop plants

In further greenhouse experiments, seeds of a substantial number of crop plants and weeds were placed in sandy loam soil and covered with soil.

Some of the pots were treated immediately as described under 1., and the remaining pots were placed in a greenhouse until the plants had developed two to three true leaves and then sprayed with various dosages of the substances according to the invention, as described under 2.

Visual scoring four to five weeks after the application and after the plants had been in the greenhouse revealed that the compounds according on the invention did not inflict any damage on dicotyledon crops such as, for example, soya, cotton, oilseed rape, sugar beet and potatoes when used pre- and post-emergence, even when high dosages of active substance were used. Moreover, some substances also left Gramineae crops such as, for example, barley, wheat, rye, Sorghum species, maize or rice unharmed. The compounds according to the invention therefore have a high selectivity when used to control undesired plant growth in agricultural crops. Compared with the compound of US-A-4,566,898 (cf. compound of the formula (3)) or Example 80 of EP-A-0,291,851, the compounds of the formula I according to the invention generally exhibit a better selectivity, in particular in the control of problem weeds such as Galium aparine or Echinochloa crus-galli in crops of useful plants.

4. Herbicidal effect when used in rice

Tubers and rhizomes or young plants or seeds of various rice weeds such as Cyperus species, Eleocharis, Scirpus and Echinochloa were placed or planted in sealed plastic pots containing special rice soil and flooded with water up to 1 cm above soil level. The same procedure was applied to rice plants.

Used pre-emergence, i.e. 3-4 days after transplanting, the compounds according to the invention were poured into the stagnant water in the form of aqueous suspensions or emulsions, or scattered into the water in the form of granules.

In each case three weeks later, the herbicidal effect and any harmful effect on rice were scored visually. The results show that the compounds according to the invention are suitable for selective weed control in rice. Compared with rice herbicides existing to date, the compounds according to the invention are distinguished by the fact that they effectively control a large number of weeds which germinate from perennial organs, in particular also weeds which are difficult to control, while being tolerated by rice. 

We claim:
 1. A compound of formula (II) ##STR24## wherein Q is an oxygen atom, sulfur atom or a group of formula --N(R⁴)--,R⁴ is hydrogen, (C₁ -C₄)alkyl or (C₁ -C₄)alkoxy, R is hydrogen; (C₁ -C₁₂)alkyl; (C₂ -C₁₀)alkenyl; (C₂ -C₁₀)alkynyl; (C₁ -C₆)alkyl, which is monosubstituted to tetrasubstituted by radicals selected from the group consisting of halogen, (C₁ -C₄)alkoxy-, (C₁ -C₄)thio-alkyl, --CN, (C₂ -C₅)alkoxycarbonyl and (C₂ -C₆)alkenyl; (C₃ -C₈)cycloalkyl which is unsubstituted or substituted by radicals selected from the group consisting of (C₁ -C₄)-alkyl, (C₁ -C₄)alkoxy, (C₁ -C₄)alkylthio and halogen; (C₅ -C₈)cycloalkenyl; phenyl(C₁ -C₄)alkyl which is unsubstituted or substituted in the phenyl radical; or a radical of the formulae A-1 to A-10 ##STR25## and X is O, S, S(O) or SO₂, with the exception of 3-aminosulfonyl-4-iodobenzoic acid.
 2. A compound of formula (II) as claimed in claim 1, whereinR is hydrogen; (C₁ -C₆)alkyl; (C₂ -C₆)alkenyl; (C₂ -C₆)alkynyl; (C₁ -C₄)alkyl which is monosubstituted to tetrasubstituted by radicals selected from the group consisting of halogen, (C₁ -C₂)alkoxy-, (C₁ -C₂)thioalkyl, (C₂ -C₃)alkoxycarbonyl and (C₂ -C₄)alkenyl; (C₅ -C₆)cycloalkyl which is unsubstituted or substituted by radicals selected from the group consisting of (C₁ -C₄)alkyl, (C₁ -C₄)alkoxy, (C₁ -C₄)alkylthio and halogen; (C₅ -C₆)cycloalkyl; benzyl which is unsubstituted or substituted in the phenyl radical by one to three radicals selected from the group consisting of halogen, (C₁ -C₂)alkyl, (C₁ -C₂)alkoxy, (C₁ -C₂)haloalkyl, (C₁ -C₂)thioalkyl and (C₂ -C₄)alkocycarbonyl, or a radical of the formulae A-1 to A-10, as defined in claim 1, where X is O, S, S(O) or SO₂.
 3. A compound of formula (II) as claimed in claim 1, whereinR is hydrogen or (C₁ -C₂)alkyl.
 4. A compound of formula (II) as claimed in claim 1, whereinQ is an oxygen atom, and R is C₁ -C₄ -alkyl
 5. The compound of formula (II) as claimed in claim 4, which is methyl 2-aminosulfonyl-6-iodobenzoate.
 6. The compound of formula (II) as claimed in claim 4, which is ethyl 2-aminosulfonyl-6-iodobenzoate.
 7. The compound of formula (II) as claimed in claim 4, which is methyl 2-aminosulfonyl-5-iodobenzoate.
 8. The compound of formula (II) as claimed in claim 4, which is ethyl 2-aminosulfonyl-5-iodobenzoate.
 9. The compound of formula (II) as claimed in claim 4, which is isopropyl 2-aminosulfonyl-5-iodobenzoate.
 10. The compound of formula (II) as claimed in claim 4, which is methyl 2-aminosulfonyl-3-iodobenzoate.
 11. The compound of formula (II) as claimed in claim 4, which is ethyl 2-aminosulfonyl-3-iodobenzoate.
 12. The compound of formula (II) as claimed in claim 4, which is methyl 3-aminosulfonyl-2-iodobenzoate.
 13. The compound of formula (II) as claimed in claim 4, which is ethyl 3-aminosulfonyl-2-iodobenzoate.
 14. The compound of formula (II) as claimed in claim 4, which is methyl 3-aminosulfonyl-4-iodobenzoate.
 15. A sulfonyl isocyanate of formula (VI) ##STR26## wherein Q is an oxygen atom, sulfur atom or a group of formula --N(R⁴)--,R⁴ is hydrogen, (C₁ -C₄)-alkyl or (C₁ -C₄)-alkoxy, R is hydrogen; (C₁ -C₁₂)alkyl; (C₂ -C₁₀)alkenyl; (C₂ -C₁₀)alkynyl; (C₁ -C₆)alkyl, which is monosubstituted to tetrasubstituted by radicals selected from the group consisting of halogen, (C₁ -C₄)alkoxy-, (C₁ -C₄)thio-alkyl, --CN, (C₂ -C₅)alkoxycarbonyl and (C₂ -C₆)alkenyl; (C₃ -C₈)cycloalkyl which is unsubstituted or substituted by radicals selected from the group consisting of (C₁ -C₄)-alkyl, (C₁ -C₄)alkoxy, (C₁ -C₄)alkylthio and halogen; (C₅ -C₈)cycloalkenyl; phenyl(C₁ -C₄)alkyl which is unsubstituted or substituted in the phenyl radical; or a radical of the formulae A-1 to A-10 ##STR27## where X is O, S, S(O) or SO₂.
 16. A compound of formula (VI) as claimed in claim 15, whereinR is hydrogen; (C₁ -C₆)alkyl; (C₂ -C₆)alkenyl; (C₂ -C₆)alkynyl; (C₁ -C₄)alkyl which is monosubstituted to tetrasubstituted by radicals selected from the group consisting of halogen, (C₁ -C₂)alkoxy-, (C₁ -C₂)thioalkyl, (C₂ -C₃)alkoxycarbonyl and (C₂ -C₄)alkenyl; (C₅ -C₆)cycloalkyl which is unsubstituted or substituted by radicals selected from the group consisting of (C₁ -C₄)alkyl, (C₁ -C₄)alkoxy, (C₁ -C₄)alkylthio and halogen; (C₅ -C₆) cycloalkyl; benzyl which is unsubstituted or substituted in the phenyl radical by one to three radicals selected from the group consisting of halogen, (C₁ -C₂)alkyl, (C₁ -C₂)alkoxy, (C₁ -C₂)haloalkyl, (C₁ -C₂)thioalkyl and (C₂ -C₄)alkocycarbonyl, or a radical of the formulae A-1 to A-10, as defined in claim 15, where X is O, S, S(O) or SO₂.
 17. A compound of formula (VI) as claimed in claim 15, whereinQ is an oxygen atom, and R is (C₁ -C₄)alkyl.
 18. The compound of formula (VI) as claimed in claim 17, which is methyl 2-isocyanatosulfonyl-6-iodobenzoate or ethyl 2-isocyanatosulfonyl-6-iodobenzoate.
 19. The compound of formula (VI) as claimed in claim 17, which is methyl 2-isocyanatosulfonyl-4-iodobenzoate or ethyl 2-isocyanatosulfonyl-4-iodobenzoate or isopropyl 2-isocyanatosulfonyl-4-iodobenzoate.
 20. The compound of formula (VI) as claimed in claim 17, which is methyl 2-isocyanatosulfonyl-3-iodobenzoate or ethyl 2-isocyanatosulfonyl-4-iodobenzoate.
 21. The compound of formula (VI) as claimed in claim 17, which is methyl 3-isocyanatosulfonyl-2-iodobenzoate or ethyl 3-isocyanatosulfonyl-2-iodobenzoate or n-propyl 3-isocyanatosulfonyl-2-iodobenzoate or isopropyl 3-isocyanatosulfonyl-2-iodobenzoate. 